Mechanosynthesis of the metallodrug bismuth subsalicylate from Bi 2O 3 and structure of bismuth salicylate without auxiliary organic ligands

Vânia André; Andrew Hardeman; Ivan Halasz; Robin S. Stein; Graham J. Jackson; David G. Reid; Melinda J. Duer; Caroline Curfs; M. Teresa Duarte; Tomislav Friščić

doi:10.1002/anie.201103171

Mechanosynthesis of the metallodrug bismuth subsalicylate from Bi ₂O ₃ and structure of bismuth salicylate without auxiliary organic ligands

Vânia André
, Andrew Hardeman
, Ivan Halasz
, Robin S. Stein
, Graham J. Jackson
, David G. Reid
, Melinda J. Duer
, Caroline Curfs
, M. Teresa Duarte
, Tomislav Friščić^*

^*Corresponding author for this work

Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

Ground out: Mechanochemical methods gave the pharmaceutical ingredient bismuth subsalicylate, as well as bismuth disalicylate and trisalicylate directly from bismuth oxide. Structure determination by powder X-ray diffraction gave the first structure of a bismuth salicylate without auxiliary organic ligands (see picture: Bi yellow, O red, C gray, two salicylate ion coordination modes are shown in purple and green).

Original language	English
Pages (from-to)	7858-7861
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	50
Issue number	34
DOIs	https://doi.org/10.1002/anie.201103171
Publication status	Published - 16 Aug 2011

Keywords

bismuth
mechanochemistry
metallodrugs
structure elucidation
sustainable chemistry

ASJC Scopus subject areas

Catalysis
General Chemistry

Access to Document

10.1002/anie.201103171

Cite this

André, V., Hardeman, A., Halasz, I., Stein, R. S., Jackson, G. J., Reid, D. G., Duer, M. J., Curfs, C., Duarte, M. T., & Friščić, T. (2011). Mechanosynthesis of the metallodrug bismuth subsalicylate from Bi ₂O ₃ and structure of bismuth salicylate without auxiliary organic ligands. Angewandte Chemie - International Edition, 50(34), 7858-7861. https://doi.org/10.1002/anie.201103171

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abstract = "Ground out: Mechanochemical methods gave the pharmaceutical ingredient bismuth subsalicylate, as well as bismuth disalicylate and trisalicylate directly from bismuth oxide. Structure determination by powder X-ray diffraction gave the first structure of a bismuth salicylate without auxiliary organic ligands (see picture: Bi yellow, O red, C gray, two salicylate ion coordination modes are shown in purple and green).",

keywords = "bismuth, mechanochemistry, metallodrugs, structure elucidation, sustainable chemistry",

author = "V{\^a}nia Andr{\'e} and Andrew Hardeman and Ivan Halasz and Stein, \{Robin S.\} and Jackson, \{Graham J.\} and Reid, \{David G.\} and Duer, \{Melinda J.\} and Caroline Curfs and Duarte, \{M. Teresa\} and Tomislav Fri{\v s}{\v c}i{\'c}",

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language = "English",

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André, V, Hardeman, A, Halasz, I, Stein, RS, Jackson, GJ, Reid, DG, Duer, MJ, Curfs, C, Duarte, MT & Friščić, T 2011, 'Mechanosynthesis of the metallodrug bismuth subsalicylate from Bi ₂O ₃ and structure of bismuth salicylate without auxiliary organic ligands', Angewandte Chemie - International Edition, vol. 50, no. 34, pp. 7858-7861. https://doi.org/10.1002/anie.201103171

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AU - André, Vânia

AU - Hardeman, Andrew

AU - Halasz, Ivan

AU - Stein, Robin S.

AU - Jackson, Graham J.

AU - Reid, David G.

AU - Duer, Melinda J.

AU - Curfs, Caroline

AU - Duarte, M. Teresa

AU - Friščić, Tomislav

PY - 2011/8/16

Y1 - 2011/8/16

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AB - Ground out: Mechanochemical methods gave the pharmaceutical ingredient bismuth subsalicylate, as well as bismuth disalicylate and trisalicylate directly from bismuth oxide. Structure determination by powder X-ray diffraction gave the first structure of a bismuth salicylate without auxiliary organic ligands (see picture: Bi yellow, O red, C gray, two salicylate ion coordination modes are shown in purple and green).

KW - bismuth

KW - mechanochemistry

KW - metallodrugs

KW - structure elucidation

KW - sustainable chemistry

UR - https://www.scopus.com/pages/publications/80051713347

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