Kinetics and products of the IO + BrO reaction

D.M. Rowley; W.J. Bloss; R.A. Cox; R.L. Jones

doi:10.1021/jp004494y

Kinetics and products of the IO + BrO reaction

D.M. Rowley, W.J. Bloss, R.A. Cox, R.L. Jones

Earth and Environmental Sciences

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Abstract

The kinetics and products of the IO + BrO reaction were discussed. The reaction was studied using the technique of laser flash photolysis with kinetic ultraviolet (UV) absorption spectroscopy. No direct measurement of I or Br was performed. IBr was observed as a minor product (k/k <0.2). No evidence of OBrO formation was observed (k/k <0.15). The results were compared with previous studies of the IO + BrO reaction, and the atmospheric implications were briefly discussed.

Original language	English
Pages (from-to)	7855-7864
Number of pages	10
Journal	The Journal of Physical Chemistry A
Volume	105
Issue number	33
DOIs	https://doi.org/10.1021/jp004494y
Publication status	Published - 23 Aug 2001

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title = "Kinetics and products of the IO + BrO reaction",

abstract = "The kinetics and products of the IO + BrO reaction were discussed. The reaction was studied using the technique of laser flash photolysis with kinetic ultraviolet (UV) absorption spectroscopy. No direct measurement of I or Br was performed. IBr was observed as a minor product (k/k <0.2). No evidence of OBrO formation was observed (k/k <0.15). The results were compared with previous studies of the IO + BrO reaction, and the atmospheric implications were briefly discussed.",

author = "D.M. Rowley and W.J. Bloss and R.A. Cox and R.L. Jones",

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AU - Rowley, D.M.

AU - Bloss, W.J.

AU - Cox, R.A.

AU - Jones, R.L.

PY - 2001/8/23

Y1 - 2001/8/23

N2 - The kinetics and products of the IO + BrO reaction were discussed. The reaction was studied using the technique of laser flash photolysis with kinetic ultraviolet (UV) absorption spectroscopy. No direct measurement of I or Br was performed. IBr was observed as a minor product (k/k <0.2). No evidence of OBrO formation was observed (k/k <0.15). The results were compared with previous studies of the IO + BrO reaction, and the atmospheric implications were briefly discussed.

AB - The kinetics and products of the IO + BrO reaction were discussed. The reaction was studied using the technique of laser flash photolysis with kinetic ultraviolet (UV) absorption spectroscopy. No direct measurement of I or Br was performed. IBr was observed as a minor product (k/k <0.2). No evidence of OBrO formation was observed (k/k <0.15). The results were compared with previous studies of the IO + BrO reaction, and the atmospheric implications were briefly discussed.

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DO - 10.1021/jp004494y

M3 - Article

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VL - 105

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EP - 7864

JO - The Journal of Physical Chemistry A

JF - The Journal of Physical Chemistry A

IS - 33

ER -

Kinetics and products of the IO + BrO reaction

Abstract

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