Intramolecular hydrogen bonding in dibenzyl 2,2′-(propane-1,3- diyldiimino)bis(cyclopent-1-ene-1-carbodithioate)

Ricardo R. Contreras, Bernardo Fontal, Isoida Romero, Reinaldo Atencio, Alexander Briceño*

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

2 Citations (Scopus)

Abstract

The title proligand, C29H34S4, exhibits two kinds of intramolecular hydrogen bonds. N-H⋯S and C-H⋯S, described by the graph-set symbols S(6) and S(5), respectively. The structural parameters of the molecule suggest a partial electron delocalization involving the nitrogen lone pair, the cyclopentene ring and the carbodithioate group. In the crystal structure, the molecules are held together mainly by C-H⋯π and van der Waals interactions.

Original languageEnglish
JournalActa Crystallographica Section E: Structure Reports Online
Volume62
Issue number1
DOIs
Publication statusPublished - 1 Jan 2006
Externally publishedYes

ASJC Scopus subject areas

  • General Chemistry
  • General Materials Science
  • Condensed Matter Physics

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