Independent Control of Elastomer Properties through Stereocontrolled Synthesis

Craig A Bell, Jiayi Yu, Ian A Barker, Vinh X Truong, Zhen Cao, Andrey V Dobrinyin, Matthew L Becker, Andrew P Dove

Research output: Contribution to journalArticlepeer-review

22 Citations (Scopus)
117 Downloads (Pure)


In most synthetic elastomers, changing the physical properties by monomer choice also results in a change to the crystallinity of the material, which manifests through alteration of its mechanical performance. Using organocatalyzed stereospecific additions of thiols to activated alkynes, high-molar-mass elastomers were isolated via step-growth polymerization. The resulting controllable double-bond stereochemistry defines the crystallinity and the concomitant mechanical properties as well as enabling the synthesis of materials that retain their excellent mechanical properties through changing monomer composition. Using this approach to elastomer synthesis, further end group modification and toughening through vulcanization strategies are also possible. The organocatalytic control of stereochemistry opens the realm to a new and easily scalable class of elastomers that will have unique chemical handles for functionalization and post synthetic processing.

Original languageEnglish
Pages (from-to)13076-13080
Number of pages5
JournalAngewandte Chemie (International Edition)
Issue number42
Early online date6 Oct 2016
Publication statusPublished - 10 Oct 2016


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