Hydroformylation of naphthas with a rhodium complex in biphasic medium

Marisela Reyes; Daniel Mercades; Bernardo Fontal; Trino Suárez; Fernando Bellandi; Ricardo R. Contreras; Isolda Romero; Yuraima Fonseca; Pedro Cancines

doi:10.1007/s11144-007-5023-6

Hydroformylation of naphthas with a rhodium complex in biphasic medium

Marisela Reyes^*
, Daniel Mercades
, Bernardo Fontal
, Trino Suárez
, Fernando Bellandi
, Ricardo R. Contreras
, Isolda Romero
, Yuraima Fonseca
, Pedro Cancines

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

8 Citations (Scopus)

Abstract

The chlorocarbonyl bis-[butylphenyl (meta-sulfonate-phenyl)phosphine] rhodium (I) complex shows catalytic hydroformylation activity in toluene/water biphasic medium for 1-hexene, cyclohexene, 2,3-dimethyl-2-butene and 2-methyl-2-pentene, their binary mixtures and a real Venezuelan naphtha, under standardized reaction conditions (1000 psi of syngas (1:1 H₂/CO), 100°C, substrate/catalyst molar ratio (600:1) and 4 h reaction time), obtaining high percent conversion to oxygenated products.

Original language	English
Pages (from-to)	347-354
Number of pages	8
Journal	Reaction Kinetics and Catalysis Letters
Volume	90
Issue number	2
DOIs	https://doi.org/10.1007/s11144-007-5023-6
Publication status	Published - 1 Apr 2007
Externally published	Yes

Keywords

Biphasic reaction
Hydroformylation
Naphtha
Rh complexes

ASJC Scopus subject areas

Catalysis
Physical and Theoretical Chemistry

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10.1007/s11144-007-5023-6

Cite this

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title = "Hydroformylation of naphthas with a rhodium complex in biphasic medium",

abstract = "The chlorocarbonyl bis-[butylphenyl (meta-sulfonate-phenyl)phosphine] rhodium (I) complex shows catalytic hydroformylation activity in toluene/water biphasic medium for 1-hexene, cyclohexene, 2,3-dimethyl-2-butene and 2-methyl-2-pentene, their binary mixtures and a real Venezuelan naphtha, under standardized reaction conditions (1000 psi of syngas (1:1 H2/CO), 100°C, substrate/catalyst molar ratio (600:1) and 4 h reaction time), obtaining high percent conversion to oxygenated products.",

keywords = "Biphasic reaction, Hydroformylation, Naphtha, Rh complexes",

author = "Marisela Reyes and Daniel Mercades and Bernardo Fontal and Trino Su{\'a}rez and Fernando Bellandi and Contreras, \{Ricardo R.\} and Isolda Romero and Yuraima Fonseca and Pedro Cancines",

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doi = "10.1007/s11144-007-5023-6",

language = "English",

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journal = "Reaction Kinetics and Catalysis Letters",

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TY - JOUR

T1 - Hydroformylation of naphthas with a rhodium complex in biphasic medium

AU - Reyes, Marisela

AU - Mercades, Daniel

AU - Fontal, Bernardo

AU - Suárez, Trino

AU - Bellandi, Fernando

AU - Contreras, Ricardo R.

AU - Romero, Isolda

AU - Fonseca, Yuraima

AU - Cancines, Pedro

PY - 2007/4/1

Y1 - 2007/4/1

N2 - The chlorocarbonyl bis-[butylphenyl (meta-sulfonate-phenyl)phosphine] rhodium (I) complex shows catalytic hydroformylation activity in toluene/water biphasic medium for 1-hexene, cyclohexene, 2,3-dimethyl-2-butene and 2-methyl-2-pentene, their binary mixtures and a real Venezuelan naphtha, under standardized reaction conditions (1000 psi of syngas (1:1 H2/CO), 100°C, substrate/catalyst molar ratio (600:1) and 4 h reaction time), obtaining high percent conversion to oxygenated products.

AB - The chlorocarbonyl bis-[butylphenyl (meta-sulfonate-phenyl)phosphine] rhodium (I) complex shows catalytic hydroformylation activity in toluene/water biphasic medium for 1-hexene, cyclohexene, 2,3-dimethyl-2-butene and 2-methyl-2-pentene, their binary mixtures and a real Venezuelan naphtha, under standardized reaction conditions (1000 psi of syngas (1:1 H2/CO), 100°C, substrate/catalyst molar ratio (600:1) and 4 h reaction time), obtaining high percent conversion to oxygenated products.

KW - Biphasic reaction

KW - Hydroformylation

KW - Naphtha

KW - Rh complexes

UR - https://www.scopus.com/pages/publications/34147131301

U2 - 10.1007/s11144-007-5023-6

DO - 10.1007/s11144-007-5023-6

M3 - Article

AN - SCOPUS:34147131301

SN - 0133-1736

VL - 90

SP - 347

EP - 354

JO - Reaction Kinetics and Catalysis Letters

JF - Reaction Kinetics and Catalysis Letters

IS - 2

ER -

Hydroformylation of naphthas with a rhodium complex in biphasic medium

Abstract

Keywords

ASJC Scopus subject areas

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