Abstract
Reversible hydrogen storage under ambient conditions has been identified as a major bottleneck in enabling a future hydrogen economy. Herein, we report an amorphous vanadium(III) alkyl hydride gel that binds hydrogen through the Kubas interaction. The material possesses a gravimetric adsorption capacity of 5.42 wt % H2 at 120 bar and 298 K reversibly at saturation with no loss of capacity after ten cycles. This corresponds to a volumetric capacity of 75.4 kgH2 m-3. Raman experiments at 100 bar confirm that Kubas binding is involved in the adsorption mechanism. The material possesses an enthalpy of H2 adsorption of +0.52 kJ mol-1 H2, as measured directly by calorimetry, and this is practical for use in a vehicles without a complex heat management system.
Original language | English |
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Pages (from-to) | 822-828 |
Number of pages | 7 |
Journal | ChemPhysChem |
Volume | 17 |
Issue number | 6 |
Early online date | 20 Jan 2016 |
DOIs | |
Publication status | Published - 16 Mar 2016 |
Keywords
- hydrides
- hydrogen storage
- materials science
- Raman spectroscopy
- transition metals
ASJC Scopus subject areas
- Physical and Theoretical Chemistry
- Atomic and Molecular Physics, and Optics