Hierarchical self-assembly of colloidal magnetic particles into reconfigurable spherical structures

Colloidal self-assembly has enormous potential as a bottom-up means of structure fabrication. Here we demonstrate hierarchical self-assembly of rationally designed charge-stabilised colloidal magnetic particles into ground state structures that are topologically equivalent to a snub cube and a snub dodecahedron, the only two chiral Archimedean solids, for size-selected clusters. These spherical structures open up in response to an external magnetic field and demonstrate controllable porosity. Such features are critical to their applications as functional materials.