Facile Mechanochemical Reduction and Lithium-Ion Doping of Transition-Metal Oxides

Nathan Davison; Tanima Khatun; Isabel Arce-Garcia; Jamie A. Gould; James A. Dawson; Erli Lu

doi:10.1002/ejic.202300344

Facile Mechanochemical Reduction and Lithium-Ion Doping of Transition-Metal Oxides

Nathan Davison
, Tanima Khatun
, Isabel Arce-Garcia
, Jamie A. Gould^*
, James A. Dawson^*
, Erli Lu^*

^*Corresponding author for this work

Chemistry

Research output: Contribution to journal › Article › peer-review

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Abstract

Transition-metal oxides (MO_x) play essential roles in chemistry, catalysis, materials science and metallurgy. The MO_x reduction and doping are two ubiquitous reactions in academic research and industrial manufacturing, but they are notoriously energy-demanding and require harsh conditions (high temperatures, long durations). In this work, facilitated by mechanochemical ball milling, we report a new route to conduct MO_x reduction and doping at room temperature within 20 minutes enabled by mechanochemical ball milling and lithium metal.

Original language	English
Article number	e202300344
Number of pages	6
Journal	European Journal of Inorganic Chemistry
Volume	26
Issue number	35
Early online date	6 Oct 2023
DOIs	https://doi.org/10.1002/ejic.202300344
Publication status	Published - 12 Dec 2023

Keywords

cobalt oxide
doping
lithium
mechanochemistry
nickel oxide
reduction

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title = "Facile Mechanochemical Reduction and Lithium-Ion Doping of Transition-Metal Oxides",

abstract = "Transition-metal oxides (MOx) play essential roles in chemistry, catalysis, materials science and metallurgy. The MOx reduction and doping are two ubiquitous reactions in academic research and industrial manufacturing, but they are notoriously energy-demanding and require harsh conditions (high temperatures, long durations). In this work, facilitated by mechanochemical ball milling, we report a new route to conduct MOx reduction and doping at room temperature within 20 minutes enabled by mechanochemical ball milling and lithium metal.",

keywords = "cobalt oxide, doping, lithium, mechanochemistry, nickel oxide, reduction",

author = "Nathan Davison and Tanima Khatun and Isabel Arce-Garcia and Gould, \{Jamie A.\} and Dawson, \{James A.\} and Erli Lu",

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T1 - Facile Mechanochemical Reduction and Lithium-Ion Doping of Transition-Metal Oxides

AU - Davison, Nathan

AU - Khatun, Tanima

AU - Arce-Garcia, Isabel

AU - Gould, Jamie A.

AU - Dawson, James A.

AU - Lu, Erli

PY - 2023/12/12

Y1 - 2023/12/12

N2 - Transition-metal oxides (MOx) play essential roles in chemistry, catalysis, materials science and metallurgy. The MOx reduction and doping are two ubiquitous reactions in academic research and industrial manufacturing, but they are notoriously energy-demanding and require harsh conditions (high temperatures, long durations). In this work, facilitated by mechanochemical ball milling, we report a new route to conduct MOx reduction and doping at room temperature within 20 minutes enabled by mechanochemical ball milling and lithium metal.

AB - Transition-metal oxides (MOx) play essential roles in chemistry, catalysis, materials science and metallurgy. The MOx reduction and doping are two ubiquitous reactions in academic research and industrial manufacturing, but they are notoriously energy-demanding and require harsh conditions (high temperatures, long durations). In this work, facilitated by mechanochemical ball milling, we report a new route to conduct MOx reduction and doping at room temperature within 20 minutes enabled by mechanochemical ball milling and lithium metal.

KW - cobalt oxide

KW - doping

KW - lithium

KW - mechanochemistry

KW - nickel oxide

KW - reduction

U2 - 10.1002/ejic.202300344

DO - 10.1002/ejic.202300344

M3 - Article

SN - 1434-1948

VL - 26

JO - European Journal of Inorganic Chemistry

JF - European Journal of Inorganic Chemistry

IS - 35

M1 - e202300344

ER -

Facile Mechanochemical Reduction and Lithium-Ion Doping of Transition-Metal Oxides

Abstract

Keywords

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