Exploiting the Curtin-Hammett principle-recognition-mediated acceleration of an aldol reaction

Sarah Howell; Peter Ashton; Neil Spencer; D Philp

doi:10.1021/ol006821q

Exploiting the Curtin-Hammett principle-recognition-mediated acceleration of an aldol reaction

Sarah Howell
, Peter Ashton
, Neil Spencer
, D Philp

Chemistry

Research output: Contribution to journal › Article

7 Citations (Scopus)

Abstract

[GRAPHICS] Curtin-Hammett-Winstein-Holness kinetics are exploited in the acceleration of the aldol reaction between formylbenzo-15-crown-5 and acetylbenzo-15-crown-5. Potassium cations facilitate this acceleration through the fast, reversible formation of a 1:1:1 sandwich complex between the crown ethers and the metal cation.

Original language	English
Pages (from-to)	353-356
Number of pages	4
Journal	Organic Letters
Volume	3
Issue number	3
DOIs	https://doi.org/10.1021/ol006821q
Publication status	Published - 1 Feb 2001

Access to Document

10.1021/ol006821q

Cite this

@article{69baec3c80af4469996aef572b990655,

title = "Exploiting the Curtin-Hammett principle-recognition-mediated acceleration of an aldol reaction",

abstract = "[GRAPHICS] Curtin-Hammett-Winstein-Holness kinetics are exploited in the acceleration of the aldol reaction between formylbenzo-15-crown-5 and acetylbenzo-15-crown-5. Potassium cations facilitate this acceleration through the fast, reversible formation of a 1:1:1 sandwich complex between the crown ethers and the metal cation.",

author = "Sarah Howell and Peter Ashton and Neil Spencer and D Philp",

year = "2001",

month = feb,

day = "1",

doi = "10.1021/ol006821q",

language = "English",

volume = "3",

pages = "353--356",

journal = "Organic Letters",

publisher = "American Chemical Society",

number = "3",

}

TY - JOUR

T1 - Exploiting the Curtin-Hammett principle-recognition-mediated acceleration of an aldol reaction

AU - Howell, Sarah

AU - Ashton, Peter

AU - Spencer, Neil

AU - Philp, D

PY - 2001/2/1

Y1 - 2001/2/1

N2 - [GRAPHICS] Curtin-Hammett-Winstein-Holness kinetics are exploited in the acceleration of the aldol reaction between formylbenzo-15-crown-5 and acetylbenzo-15-crown-5. Potassium cations facilitate this acceleration through the fast, reversible formation of a 1:1:1 sandwich complex between the crown ethers and the metal cation.

AB - [GRAPHICS] Curtin-Hammett-Winstein-Holness kinetics are exploited in the acceleration of the aldol reaction between formylbenzo-15-crown-5 and acetylbenzo-15-crown-5. Potassium cations facilitate this acceleration through the fast, reversible formation of a 1:1:1 sandwich complex between the crown ethers and the metal cation.

U2 - 10.1021/ol006821q

DO - 10.1021/ol006821q

M3 - Article

C2 - 11428012

VL - 3

SP - 353

EP - 356

JO - Organic Letters

JF - Organic Letters

IS - 3

ER -

Exploiting the Curtin-Hammett principle-recognition-mediated acceleration of an aldol reaction

Abstract

Access to Document

Fingerprint

Cite this