Exploiting the Curtin-Hammett principle-recognition-mediated acceleration of an aldol reaction

Sarah Howell; Peter Ashton; Neil Spencer; D Philp

doi:10.1021/ol006821q

Exploiting the Curtin-Hammett principle-recognition-mediated acceleration of an aldol reaction

Sarah Howell, Peter Ashton, Neil Spencer, D Philp

Chemistry

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7 Citations (Scopus)

Abstract

[GRAPHICS] Curtin-Hammett-Winstein-Holness kinetics are exploited in the acceleration of the aldol reaction between formylbenzo-15-crown-5 and acetylbenzo-15-crown-5. Potassium cations facilitate this acceleration through the fast, reversible formation of a 1:1:1 sandwich complex between the crown ethers and the metal cation.

Original language	English
Pages (from-to)	353-356
Number of pages	4
Journal	Organic Letters
Volume	3
Issue number	3
DOIs	https://doi.org/10.1021/ol006821q
Publication status	Published - 1 Feb 2001

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title = "Exploiting the Curtin-Hammett principle-recognition-mediated acceleration of an aldol reaction",

abstract = "[GRAPHICS] Curtin-Hammett-Winstein-Holness kinetics are exploited in the acceleration of the aldol reaction between formylbenzo-15-crown-5 and acetylbenzo-15-crown-5. Potassium cations facilitate this acceleration through the fast, reversible formation of a 1:1:1 sandwich complex between the crown ethers and the metal cation.",

author = "Sarah Howell and Peter Ashton and Neil Spencer and D Philp",

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AU - Ashton, Peter

AU - Spencer, Neil

AU - Philp, D

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N2 - [GRAPHICS] Curtin-Hammett-Winstein-Holness kinetics are exploited in the acceleration of the aldol reaction between formylbenzo-15-crown-5 and acetylbenzo-15-crown-5. Potassium cations facilitate this acceleration through the fast, reversible formation of a 1:1:1 sandwich complex between the crown ethers and the metal cation.

AB - [GRAPHICS] Curtin-Hammett-Winstein-Holness kinetics are exploited in the acceleration of the aldol reaction between formylbenzo-15-crown-5 and acetylbenzo-15-crown-5. Potassium cations facilitate this acceleration through the fast, reversible formation of a 1:1:1 sandwich complex between the crown ethers and the metal cation.

U2 - 10.1021/ol006821q

DO - 10.1021/ol006821q

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JO - Organic Letters

JF - Organic Letters

IS - 3

ER -

Exploiting the Curtin-Hammett principle-recognition-mediated acceleration of an aldol reaction

Abstract

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