Effect of gassing rate on solid-liquid mass transfer coefficients and particle slip velocities in stirred tank reactors

Robert Fishwick, John Winterbottom, EH Stitt

Research output: Contribution to journalArticle

19 Citations (Scopus)

Abstract

While solid-liquid dispersion in mechanically agitated vessels has been widely investigated, the suspension of particles with simultaneous gas dispersion is, however, less well understood. A consideration of the gassing rate is of particular importance when designing "dead-end" batch reactors. Solid-liquid mass transfer coefficients were determined using the technique of dissolving a sparingly soluble solid, salicylic acid loaded onto silica gel, in water. Mass transfer was found to be dependent on a variety of geometric, physical and hydrodynamic properties; with the significant exception of agitation speed the influence of the latter properties was independent of gas dispersion. Flow visualisation with positron emission particle tracking has been used alongside the mass transfer measurements to study the effects of gas injection on the liquid flow patterns and the solid-liquid slip velocities. Time-averaged relative slip velocities were determined by simple subtraction of the data obtained using a neutrally buoyant particle. Gas dispersion was found to affect the particle-liquid slip velocity, explaining the mass transfer coefficient trends observed. While only a small diameter vessel has been used it does point to considerable non-uniformity of mass transfer in larger vessels. (C) 2003 Elsevier Science Ltd. All rights reserved.
Original languageEnglish
Pages (from-to)1087-1093
Number of pages7
JournalChemical Engineering Science
Volume58
Issue number3-6
DOIs
Publication statusPublished - 1 Mar 2003

Keywords

  • multiphase reactors
  • slip velocity
  • hydrodynamics
  • visualisation
  • mass transfer
  • stirred vessels

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