Dual effect of thiol addition on fluorescent polymeric micelles: ON-to-OFF emissive switch and morphology transition

Anne B. Mabire; Mathew P. Robin; Helen Willcock; Anais Pitto-Barry; Nigel Kirby; Rachel K. O'Reilly

doi:10.1039/c4cc04713c

Dual effect of thiol addition on fluorescent polymeric micelles: ON-to-OFF emissive switch and morphology transition

Anne B. Mabire, Mathew P. Robin, Helen Willcock, Anais Pitto-Barry, Nigel Kirby, Rachel K. O'Reilly

Chemistry

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Abstract

The morphology transition from micelles to vesicles of a solution-state self-assembled block copolymer, containing a fluorescent dye at the core–shell interface, has been induced by an addition–elimination reaction using a thiol, and has been shown to be coupled to a simultaneous ON-to-OFF switch in particle fluorescence.

Original language	English
Pages (from-to)	11492-11495
Number of pages	4
Journal	Chemical Communications
Volume	50
Issue number	78
DOIs	https://doi.org/10.1039/c4cc04713c
Publication status	Published - 7 Aug 2014

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abstract = "The morphology transition from micelles to vesicles of a solution-state self-assembled block copolymer, containing a fluorescent dye at the core–shell interface, has been induced by an addition–elimination reaction using a thiol, and has been shown to be coupled to a simultaneous ON-to-OFF switch in particle fluorescence.",

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AU - Pitto-Barry, Anais

AU - Kirby, Nigel

AU - O'Reilly, Rachel K.

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AB - The morphology transition from micelles to vesicles of a solution-state self-assembled block copolymer, containing a fluorescent dye at the core–shell interface, has been induced by an addition–elimination reaction using a thiol, and has been shown to be coupled to a simultaneous ON-to-OFF switch in particle fluorescence.

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Dual effect of thiol addition on fluorescent polymeric micelles: ON-to-OFF emissive switch and morphology transition

Abstract

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