Diols and anions can control the formation of an exciplex between a pyridinium boronic acid with an aryl group connected via a propylene linker

YJ Huang; YB Jiang; SD Bull; John S. Fossey; TD James

doi:10.1039/c0cc03099f

Diols and anions can control the formation of an exciplex between a pyridinium boronic acid with an aryl group connected via a propylene linker

YJ Huang, YB Jiang, SD Bull, John S. Fossey, TD James

Chemistry

Research output: Contribution to journal › Article › peer-review

37 Citations (Scopus)

Abstract

The exciplex formation between a pyridinium boronic acid and phenyl group connected via a propylene linker can be monitored using fluorescence. Addition of pinacol affords a cyclic boronate ester with enhanced Lewis acidity that increases the strength of its cation-π stacking interaction causing a four-fold fluorescence enhancement. © 2010 The Royal Society of Chemistry.

Original language	English
Pages (from-to)	8180-8182
Number of pages	3
Journal	Chemical Communications
Volume	46
Issue number	43
DOIs	https://doi.org/10.1039/c0cc03099f
Publication status	Published - 21 Nov 2010

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title = "Diols and anions can control the formation of an exciplex between a pyridinium boronic acid with an aryl group connected via a propylene linker",

abstract = "The exciplex formation between a pyridinium boronic acid and phenyl group connected via a propylene linker can be monitored using fluorescence. Addition of pinacol affords a cyclic boronate ester with enhanced Lewis acidity that increases the strength of its cation-π stacking interaction causing a four-fold fluorescence enhancement. {\textcopyright} 2010 The Royal Society of Chemistry.",

author = "YJ Huang and YB Jiang and SD Bull and Fossey, {John S.} and TD James",

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AU - Huang, YJ

AU - Jiang, YB

AU - Bull, SD

AU - Fossey, John S.

AU - James, TD

PY - 2010/11/21

Y1 - 2010/11/21

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AB - The exciplex formation between a pyridinium boronic acid and phenyl group connected via a propylene linker can be monitored using fluorescence. Addition of pinacol affords a cyclic boronate ester with enhanced Lewis acidity that increases the strength of its cation-π stacking interaction causing a four-fold fluorescence enhancement. © 2010 The Royal Society of Chemistry.

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DO - 10.1039/c0cc03099f

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JO - Chemical Communications

JF - Chemical Communications

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ER -

Diols and anions can control the formation of an exciplex between a pyridinium boronic acid with an aryl group connected via a propylene linker

Abstract

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