Desymmetrisation of aromatic diamines and synthesis of non-symmetrical thiourea derivatives by click-mechanochemistry

Vjekoslav Štrukil; Davor Margetic; Marina D. Igrc; Mirjana Eckert-Maksic; Tomislav Frišcic

doi:10.1039/c2cc34013e

Desymmetrisation of aromatic diamines and synthesis of non-symmetrical thiourea derivatives by click-mechanochemistry

Vjekoslav Štrukil, Davor Margetic, Marina D. Igrc, Mirjana Eckert-Maksic^*, Tomislav Frišcic

^*Corresponding author for this work

Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

Ortho- and para-Phenylenediamines were desymmetrised and quantitatively transformed into mono- and bis-(thio)ureas or mixed thiourea–ureas through a one-pot mechanochemical click reaction sequence; mechanochemical desymmetrisation proceeds quantitatively without excess reagents and allows the controlled extension of a molecular structure by combining normally competing reactions.

Original language	English
Pages (from-to)	9705-9707
Number of pages	3
Journal	Chemical Communications
Volume	48
Issue number	78
DOIs	https://doi.org/10.1039/c2cc34013e
Publication status	Published - 5 Sept 2012

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
General Chemistry
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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10.1039/c2cc34013e

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title = "Desymmetrisation of aromatic diamines and synthesis of non-symmetrical thiourea derivatives by click-mechanochemistry",

abstract = "Ortho- and para-Phenylenediamines were desymmetrised and quantitatively transformed into mono- and bis-(thio)ureas or mixed thiourea–ureas through a one-pot mechanochemical click reaction sequence; mechanochemical desymmetrisation proceeds quantitatively without excess reagents and allows the controlled extension of a molecular structure by combining normally competing reactions.",

author = "Vjekoslav {\v S}trukil and Davor Margetic and Igrc, \{Marina D.\} and Mirjana Eckert-Maksic and Tomislav Fri{\v s}cic",

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T1 - Desymmetrisation of aromatic diamines and synthesis of non-symmetrical thiourea derivatives by click-mechanochemistry

AU - Štrukil, Vjekoslav

AU - Margetic, Davor

AU - Igrc, Marina D.

AU - Eckert-Maksic, Mirjana

AU - Frišcic, Tomislav

PY - 2012/9/5

Y1 - 2012/9/5

N2 - Ortho- and para-Phenylenediamines were desymmetrised and quantitatively transformed into mono- and bis-(thio)ureas or mixed thiourea–ureas through a one-pot mechanochemical click reaction sequence; mechanochemical desymmetrisation proceeds quantitatively without excess reagents and allows the controlled extension of a molecular structure by combining normally competing reactions.

AB - Ortho- and para-Phenylenediamines were desymmetrised and quantitatively transformed into mono- and bis-(thio)ureas or mixed thiourea–ureas through a one-pot mechanochemical click reaction sequence; mechanochemical desymmetrisation proceeds quantitatively without excess reagents and allows the controlled extension of a molecular structure by combining normally competing reactions.

UR - https://www.scopus.com/pages/publications/84866250876

U2 - 10.1039/c2cc34013e

DO - 10.1039/c2cc34013e

M3 - Article

C2 - 22914574

AN - SCOPUS:84866250876

SN - 1359-7345

VL - 48

SP - 9705

EP - 9707

JO - Chemical Communications

JF - Chemical Communications

IS - 78

ER -

Desymmetrisation of aromatic diamines and synthesis of non-symmetrical thiourea derivatives by click-mechanochemistry

Abstract

ASJC Scopus subject areas

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