Copper(I) complexes as alternatives to iridium(III) complexes for highly efficient oxygen sensing

Santiago Medina-Rodríguez; Francisco J Orriach-Fernández; Christopher Poole; Prashant Kumar; Ángel de la Torre-Vega; Jorge F Fernández-Sánchez; Etienne Baranoff; Alberto Fernández-Gutiérrez

doi:10.1039/c5cc04326c

Copper(I) complexes as alternatives to iridium(III) complexes for highly efficient oxygen sensing

Santiago Medina-Rodríguez
, Francisco J Orriach-Fernández
, Christopher Poole
, Prashant Kumar
, Ángel de la Torre-Vega
, Jorge F Fernández-Sánchez
, Etienne Baranoff
, Alberto Fernández-Gutiérrez

Chemistry

Research output: Contribution to journal › Article › peer-review

19 Citations (Scopus)

232 Downloads (Pure)

Abstract

The complex [Cu(xantphos)(dmp)][PF6] (dmp = 2,9-dimethyl-1,10-phenanthroline) in a nanostructured metal oxyde matrix shows better sensitivity to oxygen (KSV = 9.74 ± 0.87 kPa(-1) between 0 and 1 kPa pO2 and 5.59 ± 0.15 kPa(-1) between 0 and 10 kPa pO2) than cyclometallated iridium complexes in the same conditions.

Original language	English
Pages (from-to)	11401-11404
Number of pages	4
Journal	Chemical Communications
Volume	51
Issue number	57
Early online date	10 Jun 2015
DOIs	https://doi.org/10.1039/c5cc04326c
Publication status	Published - 21 Jul 2015

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10.1039/c5cc04326c

Medina_Rodriguez_et_al_2015_Copper(I)_complexes_alternatives_Chemical_Communications
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Cite this

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title = "Copper(I) complexes as alternatives to iridium(III) complexes for highly efficient oxygen sensing",

abstract = "The complex [Cu(xantphos)(dmp)][PF6] (dmp = 2,9-dimethyl-1,10-phenanthroline) in a nanostructured metal oxyde matrix shows better sensitivity to oxygen (KSV = 9.74 ± 0.87 kPa(-1) between 0 and 1 kPa pO2 and 5.59 ± 0.15 kPa(-1) between 0 and 10 kPa pO2) than cyclometallated iridium complexes in the same conditions.",

author = "Santiago Medina-Rodr{\'i}guez and Orriach-Fern{\'a}ndez, \{Francisco J\} and Christopher Poole and Prashant Kumar and \{de la Torre-Vega\}, {\'A}ngel and Fern{\'a}ndez-S{\'a}nchez, \{Jorge F\} and Etienne Baranoff and Alberto Fern{\'a}ndez-Guti{\'e}rrez",

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doi = "10.1039/c5cc04326c",

language = "English",

volume = "51",

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TY - JOUR

T1 - Copper(I) complexes as alternatives to iridium(III) complexes for highly efficient oxygen sensing

AU - Medina-Rodríguez, Santiago

AU - Orriach-Fernández, Francisco J

AU - Poole, Christopher

AU - Kumar, Prashant

AU - de la Torre-Vega, Ángel

AU - Fernández-Sánchez, Jorge F

AU - Baranoff, Etienne

AU - Fernández-Gutiérrez, Alberto

PY - 2015/7/21

Y1 - 2015/7/21

N2 - The complex [Cu(xantphos)(dmp)][PF6] (dmp = 2,9-dimethyl-1,10-phenanthroline) in a nanostructured metal oxyde matrix shows better sensitivity to oxygen (KSV = 9.74 ± 0.87 kPa(-1) between 0 and 1 kPa pO2 and 5.59 ± 0.15 kPa(-1) between 0 and 10 kPa pO2) than cyclometallated iridium complexes in the same conditions.

AB - The complex [Cu(xantphos)(dmp)][PF6] (dmp = 2,9-dimethyl-1,10-phenanthroline) in a nanostructured metal oxyde matrix shows better sensitivity to oxygen (KSV = 9.74 ± 0.87 kPa(-1) between 0 and 1 kPa pO2 and 5.59 ± 0.15 kPa(-1) between 0 and 10 kPa pO2) than cyclometallated iridium complexes in the same conditions.

U2 - 10.1039/c5cc04326c

DO - 10.1039/c5cc04326c

M3 - Article

C2 - 26086848

SN - 1359-7345

VL - 51

SP - 11401

EP - 11404

JO - Chemical Communications

JF - Chemical Communications

IS - 57

ER -

Copper(I) complexes as alternatives to iridium(III) complexes for highly efficient oxygen sensing

Abstract

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