Controlled nitrene transfer from a tyrosinase-like arylnitroso–copper complex

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Abstract

The reaction between p-nitrosonitrobenzene and the tetramethylpropylenediamine–copper(i) complex yields a dinuclear complex that has similar topology, electronic structure and reactivity as side-on peroxo species known in Cu/O2 chemistry.

Original languageEnglish
JournalChemical Communications
DOIs
Publication statusPublished - 2015

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