Chiral amplification in the transcription of supramolecular helicity into a polymer backbone

Andrew J. Wilson; Mitsutoshi Masuda; Rint P. Sijbesma; E. W. Meijer

doi:10.1002/anie.200462347

Chiral amplification in the transcription of supramolecular helicity into a polymer backbone

Andrew J. Wilson^*
, Mitsutoshi Masuda
, Rint P. Sijbesma
, E. W. Meijer

^*Corresponding author for this work

Chemistry

Research output: Contribution to journal › Article › peer-review

123 Citations (Scopus)

Abstract

(Figure Presented) A chiral supramolecular "sergeant" as the structure-directing agent affects the backbone stereochemistry during polymerization of the achiral "soldier" monomers. The polymer obtained shows preferred helical folding despite its mixed microstructure.

Original language	English
Pages (from-to)	2275-2279
Number of pages	5
Journal	Angewandte Chemie - International Edition
Volume	44
Issue number	15
DOIs	https://doi.org/10.1002/anie.200462347
Publication status	Published - 8 Apr 2005

Keywords

Helical structures
Polymerization
Polymers
Self-assembly
Supramolecular chemistry

ASJC Scopus subject areas

Catalysis
General Chemistry

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10.1002/anie.200462347

Cite this

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title = "Chiral amplification in the transcription of supramolecular helicity into a polymer backbone",

abstract = "(Figure Presented) A chiral supramolecular {"}sergeant{"} as the structure-directing agent affects the backbone stereochemistry during polymerization of the achiral {"}soldier{"} monomers. The polymer obtained shows preferred helical folding despite its mixed microstructure.",

keywords = "Helical structures, Polymerization, Polymers, Self-assembly, Supramolecular chemistry",

author = "Wilson, \{Andrew J.\} and Mitsutoshi Masuda and Sijbesma, \{Rint P.\} and Meijer, \{E. W.\}",

year = "2005",

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doi = "10.1002/anie.200462347",

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T1 - Chiral amplification in the transcription of supramolecular helicity into a polymer backbone

AU - Wilson, Andrew J.

AU - Masuda, Mitsutoshi

AU - Sijbesma, Rint P.

AU - Meijer, E. W.

PY - 2005/4/8

Y1 - 2005/4/8

N2 - (Figure Presented) A chiral supramolecular "sergeant" as the structure-directing agent affects the backbone stereochemistry during polymerization of the achiral "soldier" monomers. The polymer obtained shows preferred helical folding despite its mixed microstructure.

AB - (Figure Presented) A chiral supramolecular "sergeant" as the structure-directing agent affects the backbone stereochemistry during polymerization of the achiral "soldier" monomers. The polymer obtained shows preferred helical folding despite its mixed microstructure.

KW - Helical structures

KW - Polymerization

KW - Polymers

KW - Self-assembly

KW - Supramolecular chemistry

UR - https://www.scopus.com/pages/publications/17644404441

U2 - 10.1002/anie.200462347

DO - 10.1002/anie.200462347

M3 - Article

AN - SCOPUS:17644404441

SN - 1433-7851

VL - 44

SP - 2275

EP - 2279

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 15

ER -

Chiral amplification in the transcription of supramolecular helicity into a polymer backbone

Abstract

Keywords

ASJC Scopus subject areas

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