Charged cyclometalated iridium(III) complexes that have large electrochemical gap

Nail M. Shavaleev; Rosario Scopelliti; Etienne Baranoff; Michael Grätzel; Mohammad K. Nazeeruddin; Etienne Baranoff

doi:10.1016/j.ica.2011.10.052

Charged cyclometalated iridium(III) complexes that have large electrochemical gap

Nail M. Shavaleev^*
, Rosario Scopelliti
, Etienne Baranoff
, Michael Grätzel
, Mohammad K. Nazeeruddin
, Etienne Baranoff

^*Corresponding author for this work

Chemistry

Research output: Contribution to journal › Article › peer-review

10 Citations (Scopus)

Abstract

Bis-cyclometalated cationic Ir(III) diimine complexes [Ir(C^N) ₂(N^N)](PF ₆) with 1-phenylpyrazoles (C^N) and 1-(4′-tert-butyl-2′-pyridyl)pyrazole (N^N) are white solids that have absorption onset below 425 nm and electrochemical gap of up to 3.5 V.

Original language	English
Pages (from-to)	316-319
Number of pages	4
Journal	Inorganica Chimica Acta
Volume	383
DOIs	https://doi.org/10.1016/j.ica.2011.10.052
Publication status	Published - 30 Mar 2012

Keywords

Complex
Cyclometalation
Electrochemistry
Iridium
Pyrazole

ASJC Scopus subject areas

Inorganic Chemistry
Physical and Theoretical Chemistry
Materials Chemistry

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10.1016/j.ica.2011.10.052

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@article{53c8cb53ef204fd6ae69bee4f4bb4544,

title = "Charged cyclometalated iridium(III) complexes that have large electrochemical gap",

abstract = "Bis-cyclometalated cationic Ir(III) diimine complexes [Ir(C\textasciicircum{}N) 2(N\textasciicircum{}N)](PF 6) with 1-phenylpyrazoles (C\textasciicircum{}N) and 1-(4′-tert-butyl-2′-pyridyl)pyrazole (N\textasciicircum{}N) are white solids that have absorption onset below 425 nm and electrochemical gap of up to 3.5 V.",

keywords = "Complex, Cyclometalation, Electrochemistry, Iridium, Pyrazole",

author = "Shavaleev, \{Nail M.\} and Rosario Scopelliti and Etienne Baranoff and Michael Gr{\"a}tzel and Nazeeruddin, \{Mohammad K.\} and Etienne Baranoff",

year = "2012",

month = mar,

day = "30",

doi = "10.1016/j.ica.2011.10.052",

language = "English",

volume = "383",

pages = "316--319",

journal = "Inorganica Chimica Acta",

issn = "0020-1693",

publisher = "Elsevier",

}

TY - JOUR

T1 - Charged cyclometalated iridium(III) complexes that have large electrochemical gap

AU - Shavaleev, Nail M.

AU - Scopelliti, Rosario

AU - Baranoff, Etienne

AU - Grätzel, Michael

AU - Nazeeruddin, Mohammad K.

AU - Baranoff, Etienne

PY - 2012/3/30

Y1 - 2012/3/30

N2 - Bis-cyclometalated cationic Ir(III) diimine complexes [Ir(C^N) 2(N^N)](PF 6) with 1-phenylpyrazoles (C^N) and 1-(4′-tert-butyl-2′-pyridyl)pyrazole (N^N) are white solids that have absorption onset below 425 nm and electrochemical gap of up to 3.5 V.

AB - Bis-cyclometalated cationic Ir(III) diimine complexes [Ir(C^N) 2(N^N)](PF 6) with 1-phenylpyrazoles (C^N) and 1-(4′-tert-butyl-2′-pyridyl)pyrazole (N^N) are white solids that have absorption onset below 425 nm and electrochemical gap of up to 3.5 V.

KW - Complex

KW - Cyclometalation

KW - Electrochemistry

KW - Iridium

KW - Pyrazole

UR - https://www.scopus.com/pages/publications/84857233174

U2 - 10.1016/j.ica.2011.10.052

DO - 10.1016/j.ica.2011.10.052

M3 - Article

AN - SCOPUS:84857233174

SN - 0020-1693

VL - 383

SP - 316

EP - 319

JO - Inorganica Chimica Acta

JF - Inorganica Chimica Acta

ER -

Charged cyclometalated iridium(III) complexes that have large electrochemical gap

Abstract

Keywords

ASJC Scopus subject areas

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