Boride cluster fusion through copper and silver. Crystal structure of [(Ph3P)(2)N][(HRu4(CO)(12)BH)(2)Ag]

Catherine Housecroft; SM Draper; AD Hattersley; AL Rheingold

doi:10.1016/S0022-328X(00)00577-5

Boride cluster fusion through copper and silver. Crystal structure of [(Ph3P)(2)N][(HRu4(CO)(12)BH)(2)Ag]

Catherine Housecroft, SM Draper, AD Hattersley, AL Rheingold

Chemistry

Research output: Contribution to journal › Article

7 Citations (Scopus)

Abstract

Reaction of [(Ph3P)(2)N][HRu4(CO)(12)BH] with [Cu(NCMe)(4)][BF4] in the presence of [(Ph3P)(2)N]Cl leads to [(Ph3P)(2)N][HRu4(CO)(12)B)(2)Cu-4(mu -Cl)]Cl, confirmed by a single crystal structure determination. A silver analogue is produced from the reactions of [(Ph3P)(2)N][HRu4(CO)(12)BH] with [Ag(NCMe)(4)][BF4] or AgBF4, but its formation competes with that of [(Ph3P)(2)N][HRu4(CO)(12)BH)(2)Ag], the crystal structure of which has been determined. (C) 2000 Elsevier Science B.V. All rights reserved.

Original language	English
Pages (from-to)	202-207
Number of pages	6
Journal	Journal of Organometallic Chemistry
Volume	614
DOIs	https://doi.org/10.1016/S0022-328X(00)00577-5
Publication status	Published - 1 Dec 2000

Keywords

cluster fusion
copper
silver
boron
ruthenium

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10.1016/S0022-328X(00)00577-5

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title = "Boride cluster fusion through copper and silver. Crystal structure of [(Ph3P)(2)N][(HRu4(CO)(12)BH)(2)Ag]",

abstract = "Reaction of [(Ph3P)(2)N][HRu4(CO)(12)BH] with [Cu(NCMe)(4)][BF4] in the presence of [(Ph3P)(2)N]Cl leads to [(Ph3P)(2)N][HRu4(CO)(12)B)(2)Cu-4(mu -Cl)]Cl, confirmed by a single crystal structure determination. A silver analogue is produced from the reactions of [(Ph3P)(2)N][HRu4(CO)(12)BH] with [Ag(NCMe)(4)][BF4] or AgBF4, but its formation competes with that of [(Ph3P)(2)N][HRu4(CO)(12)BH)(2)Ag], the crystal structure of which has been determined. (C) 2000 Elsevier Science B.V. All rights reserved.",

keywords = "cluster fusion, copper, silver, boron, ruthenium",

author = "Catherine Housecroft and SM Draper and AD Hattersley and AL Rheingold",

year = "2000",

month = dec,

day = "1",

doi = "10.1016/S0022-328X(00)00577-5",

language = "English",

volume = "614",

pages = "202--207",

journal = "Journal of Organometallic Chemistry",

publisher = "Elsevier",

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TY - JOUR

T1 - Boride cluster fusion through copper and silver. Crystal structure of [(Ph3P)(2)N][(HRu4(CO)(12)BH)(2)Ag]

AU - Housecroft, Catherine

AU - Draper, SM

AU - Hattersley, AD

AU - Rheingold, AL

PY - 2000/12/1

Y1 - 2000/12/1

N2 - Reaction of [(Ph3P)(2)N][HRu4(CO)(12)BH] with [Cu(NCMe)(4)][BF4] in the presence of [(Ph3P)(2)N]Cl leads to [(Ph3P)(2)N][HRu4(CO)(12)B)(2)Cu-4(mu -Cl)]Cl, confirmed by a single crystal structure determination. A silver analogue is produced from the reactions of [(Ph3P)(2)N][HRu4(CO)(12)BH] with [Ag(NCMe)(4)][BF4] or AgBF4, but its formation competes with that of [(Ph3P)(2)N][HRu4(CO)(12)BH)(2)Ag], the crystal structure of which has been determined. (C) 2000 Elsevier Science B.V. All rights reserved.

AB - Reaction of [(Ph3P)(2)N][HRu4(CO)(12)BH] with [Cu(NCMe)(4)][BF4] in the presence of [(Ph3P)(2)N]Cl leads to [(Ph3P)(2)N][HRu4(CO)(12)B)(2)Cu-4(mu -Cl)]Cl, confirmed by a single crystal structure determination. A silver analogue is produced from the reactions of [(Ph3P)(2)N][HRu4(CO)(12)BH] with [Ag(NCMe)(4)][BF4] or AgBF4, but its formation competes with that of [(Ph3P)(2)N][HRu4(CO)(12)BH)(2)Ag], the crystal structure of which has been determined. (C) 2000 Elsevier Science B.V. All rights reserved.

KW - cluster fusion

KW - copper

KW - silver

KW - boron

KW - ruthenium

U2 - 10.1016/S0022-328X(00)00577-5

DO - 10.1016/S0022-328X(00)00577-5

M3 - Article

VL - 614

SP - 202

EP - 207

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

ER -

Boride cluster fusion through copper and silver. Crystal structure of [(Ph3P)(2)N][(HRu4(CO)(12)BH)(2)Ag]

Abstract

Keywords

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