Benchmarking the reproducibility of all-solid-state battery cell performance

Sebastian Puls; Elina Nazmutdinova; Fariza Kalyk; Henry M. Woolley; Jesper Frost Thomsen; Zhu Cheng; Adrien Fauchier-Magnan; Ajay Gautam; Michael Gockeln; So-Yeon Ham; Md Toukir Hasan; Min-Gi Jeong; Daiki Hiraoka; Jong Seok Kim; Tobias Kutsch; Barthélémy Lelotte; Philip Minnmann; Vanessa Miß; Kota Motohashi; Douglas Lars Nelson; Frans Ooms; Francesco Piccolo; Christian Plank; Maria Rosner; Stephanie E. Sandoval; Eva Schlautmann; Robin Schuster; Dominic Spencer-Jolly; Yipeng Sun; Bairav S. Vishnugopi; Ruizhuo Zhang; Huang Zheng; Philipp Adelhelm; Torsten Brezesinski; Peter G. Bruce; Michael Danzer; Mario El Kazzi; Hubert Gasteiger; Kelsey B. Hatzell; Akitoshi Hayashi; Felix Hippauf; Jürgen Janek; Yoon Seok Jung; Matthew T. McDowell; Ying Shirley Meng; Partha P. Mukherjee; Saneyuki Ohno; Bernhard Roling; Atsushi Sakuda; Julian Schwenzel; Xueliang Sun; Claire Villevieille; Marnix Wagemaker; Wolfgang G. Zeier; Nella M. Vargas-Barbosa

doi:10.1038/s41560-024-01634-3

Benchmarking the reproducibility of all-solid-state battery cell performance

Sebastian Puls, Elina Nazmutdinova, Fariza Kalyk, Henry M. Woolley, Jesper Frost Thomsen, Zhu Cheng, Adrien Fauchier-Magnan, Ajay Gautam, Michael Gockeln, So-Yeon Ham, Md Toukir Hasan, Min-Gi Jeong, Daiki Hiraoka, Jong Seok Kim, Tobias Kutsch, Barthélémy Lelotte, Philip Minnmann, Vanessa Miß, Kota Motohashi, Douglas Lars NelsonFrans Ooms, Francesco Piccolo, Christian Plank, Maria Rosner, Stephanie E. Sandoval, Eva Schlautmann, Robin Schuster, Dominic Spencer-Jolly, Yipeng Sun, Bairav S. Vishnugopi, Ruizhuo Zhang, Huang Zheng, Philipp Adelhelm, Torsten Brezesinski, Peter G. Bruce, Michael Danzer, Mario El Kazzi, Hubert Gasteiger, Kelsey B. Hatzell, Akitoshi Hayashi, Felix Hippauf, Jürgen Janek, Yoon Seok Jung, Matthew T. McDowell, Ying Shirley Meng, Partha P. Mukherjee, Saneyuki Ohno, Bernhard Roling, Atsushi Sakuda, Julian Schwenzel, Xueliang Sun, Claire Villevieille, Marnix Wagemaker, Wolfgang G. Zeier, Nella M. Vargas-Barbosa^*

^*Corresponding author for this work

Metallurgy and Materials

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Abstract

The interlaboratory comparability and reproducibility of all-solid-state battery cell cycling performance are poorly understood due to the lack of standardized set-ups and assembly parameters. This study quantifies the extent of this variability by providing commercially sourced battery materials—LiNi_0.6Mn_0.2Co_0.2O₂ for the positive electrode, Li₆PS₅Cl as the solid electrolyte and indium for the negative electrode—to 21 research groups. Each group was asked to use their own cell assembly protocol but follow a specific electrochemical protocol. The results show large variability in assembly and electrochemical performance, including differences in processing pressures, pressing durations and In-to-Li ratios. Despite this, an initial open circuit voltage of 2.5 and 2.7 V vs Li⁺/Li is a good predictor of successful cycling for cells using these electroactive materials. We suggest a set of parameters for reporting all-solid-state battery cycling results and advocate for reporting data in triplicate.

Original language	English
Pages (from-to)	1310-1320
Number of pages	11
Journal	Nature Energy
Volume	9
Issue number	10
Early online date	18 Sept 2024
DOIs	https://doi.org/10.1038/s41560-024-01634-3
Publication status	Published - Oct 2024

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Puls, S., Nazmutdinova, E., Kalyk, F., Woolley, H. M., Thomsen, J. F., Cheng, Z., Fauchier-Magnan, A., Gautam, A., Gockeln, M., Ham, S.-Y., Hasan, M. T., Jeong, M.-G., Hiraoka, D., Kim, J. S., Kutsch, T., Lelotte, B., Minnmann, P., Miß, V., Motohashi, K., ... Vargas-Barbosa, N. M. (2024). Benchmarking the reproducibility of all-solid-state battery cell performance. Nature Energy, 9(10), 1310-1320. https://doi.org/10.1038/s41560-024-01634-3

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title = "Benchmarking the reproducibility of all-solid-state battery cell performance",

abstract = "The interlaboratory comparability and reproducibility of all-solid-state battery cell cycling performance are poorly understood due to the lack of standardized set-ups and assembly parameters. This study quantifies the extent of this variability by providing commercially sourced battery materials—LiNi0.6Mn0.2Co0.2O2 for the positive electrode, Li6PS5Cl as the solid electrolyte and indium for the negative electrode—to 21 research groups. Each group was asked to use their own cell assembly protocol but follow a specific electrochemical protocol. The results show large variability in assembly and electrochemical performance, including differences in processing pressures, pressing durations and In-to-Li ratios. Despite this, an initial open circuit voltage of 2.5 and 2.7 V vs Li+/Li is a good predictor of successful cycling for cells using these electroactive materials. We suggest a set of parameters for reporting all-solid-state battery cycling results and advocate for reporting data in triplicate.",

author = "Sebastian Puls and Elina Nazmutdinova and Fariza Kalyk and Woolley, {Henry M.} and Thomsen, {Jesper Frost} and Zhu Cheng and Adrien Fauchier-Magnan and Ajay Gautam and Michael Gockeln and So-Yeon Ham and Hasan, {Md Toukir} and Min-Gi Jeong and Daiki Hiraoka and Kim, {Jong Seok} and Tobias Kutsch and Barth{\'e}l{\'e}my Lelotte and Philip Minnmann and Vanessa Mi{\ss} and Kota Motohashi and Nelson, {Douglas Lars} and Frans Ooms and Francesco Piccolo and Christian Plank and Maria Rosner and Sandoval, {Stephanie E.} and Eva Schlautmann and Robin Schuster and Dominic Spencer-Jolly and Yipeng Sun and Vishnugopi, {Bairav S.} and Ruizhuo Zhang and Huang Zheng and Philipp Adelhelm and Torsten Brezesinski and Bruce, {Peter G.} and Michael Danzer and {El Kazzi}, Mario and Hubert Gasteiger and Hatzell, {Kelsey B.} and Akitoshi Hayashi and Felix Hippauf and J{\"u}rgen Janek and Jung, {Yoon Seok} and McDowell, {Matthew T.} and Meng, {Ying Shirley} and Mukherjee, {Partha P.} and Saneyuki Ohno and Bernhard Roling and Atsushi Sakuda and Julian Schwenzel and Xueliang Sun and Claire Villevieille and Marnix Wagemaker and Zeier, {Wolfgang G.} and Vargas-Barbosa, {Nella M.}",

year = "2024",

month = oct,

doi = "10.1038/s41560-024-01634-3",

language = "English",

volume = "9",

pages = "1310--1320",

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issn = "2058-7546",

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Puls, S, Nazmutdinova, E, Kalyk, F, Woolley, HM, Thomsen, JF, Cheng, Z, Fauchier-Magnan, A, Gautam, A, Gockeln, M, Ham, S-Y, Hasan, MT, Jeong, M-G, Hiraoka, D, Kim, JS, Kutsch, T, Lelotte, B, Minnmann, P, Miß, V, Motohashi, K, Nelson, DL, Ooms, F, Piccolo, F, Plank, C, Rosner, M, Sandoval, SE, Schlautmann, E, Schuster, R, Spencer-Jolly, D, Sun, Y, Vishnugopi, BS, Zhang, R, Zheng, H, Adelhelm, P, Brezesinski, T, Bruce, PG, Danzer, M, El Kazzi, M, Gasteiger, H, Hatzell, KB, Hayashi, A, Hippauf, F, Janek, J, Jung, YS, McDowell, MT, Meng, YS, Mukherjee, PP, Ohno, S, Roling, B, Sakuda, A, Schwenzel, J, Sun, X, Villevieille, C, Wagemaker, M, Zeier, WG & Vargas-Barbosa, NM 2024, 'Benchmarking the reproducibility of all-solid-state battery cell performance', Nature Energy, vol. 9, no. 10, pp. 1310-1320. https://doi.org/10.1038/s41560-024-01634-3

TY - JOUR

T1 - Benchmarking the reproducibility of all-solid-state battery cell performance

AU - Puls, Sebastian

AU - Nazmutdinova, Elina

AU - Kalyk, Fariza

AU - Woolley, Henry M.

AU - Thomsen, Jesper Frost

AU - Cheng, Zhu

AU - Fauchier-Magnan, Adrien

AU - Gautam, Ajay

AU - Gockeln, Michael

AU - Ham, So-Yeon

AU - Hasan, Md Toukir

AU - Jeong, Min-Gi

AU - Hiraoka, Daiki

AU - Kim, Jong Seok

AU - Kutsch, Tobias

AU - Lelotte, Barthélémy

AU - Minnmann, Philip

AU - Miß, Vanessa

AU - Motohashi, Kota

AU - Nelson, Douglas Lars

AU - Ooms, Frans

AU - Piccolo, Francesco

AU - Plank, Christian

AU - Rosner, Maria

AU - Sandoval, Stephanie E.

AU - Schlautmann, Eva

AU - Schuster, Robin

AU - Spencer-Jolly, Dominic

AU - Sun, Yipeng

AU - Vishnugopi, Bairav S.

AU - Zhang, Ruizhuo

AU - Zheng, Huang

AU - Adelhelm, Philipp

AU - Brezesinski, Torsten

AU - Bruce, Peter G.

AU - Danzer, Michael

AU - El Kazzi, Mario

AU - Gasteiger, Hubert

AU - Hatzell, Kelsey B.

AU - Hayashi, Akitoshi

AU - Hippauf, Felix

AU - Janek, Jürgen

AU - Jung, Yoon Seok

AU - McDowell, Matthew T.

AU - Meng, Ying Shirley

AU - Mukherjee, Partha P.

AU - Ohno, Saneyuki

AU - Roling, Bernhard

AU - Sakuda, Atsushi

AU - Schwenzel, Julian

AU - Sun, Xueliang

AU - Villevieille, Claire

AU - Wagemaker, Marnix

AU - Zeier, Wolfgang G.

AU - Vargas-Barbosa, Nella M.

PY - 2024/10

Y1 - 2024/10

N2 - The interlaboratory comparability and reproducibility of all-solid-state battery cell cycling performance are poorly understood due to the lack of standardized set-ups and assembly parameters. This study quantifies the extent of this variability by providing commercially sourced battery materials—LiNi0.6Mn0.2Co0.2O2 for the positive electrode, Li6PS5Cl as the solid electrolyte and indium for the negative electrode—to 21 research groups. Each group was asked to use their own cell assembly protocol but follow a specific electrochemical protocol. The results show large variability in assembly and electrochemical performance, including differences in processing pressures, pressing durations and In-to-Li ratios. Despite this, an initial open circuit voltage of 2.5 and 2.7 V vs Li+/Li is a good predictor of successful cycling for cells using these electroactive materials. We suggest a set of parameters for reporting all-solid-state battery cycling results and advocate for reporting data in triplicate.

AB - The interlaboratory comparability and reproducibility of all-solid-state battery cell cycling performance are poorly understood due to the lack of standardized set-ups and assembly parameters. This study quantifies the extent of this variability by providing commercially sourced battery materials—LiNi0.6Mn0.2Co0.2O2 for the positive electrode, Li6PS5Cl as the solid electrolyte and indium for the negative electrode—to 21 research groups. Each group was asked to use their own cell assembly protocol but follow a specific electrochemical protocol. The results show large variability in assembly and electrochemical performance, including differences in processing pressures, pressing durations and In-to-Li ratios. Despite this, an initial open circuit voltage of 2.5 and 2.7 V vs Li+/Li is a good predictor of successful cycling for cells using these electroactive materials. We suggest a set of parameters for reporting all-solid-state battery cycling results and advocate for reporting data in triplicate.

U2 - 10.1038/s41560-024-01634-3

DO - 10.1038/s41560-024-01634-3

M3 - Article

SN - 2058-7546

VL - 9

SP - 1310

EP - 1320

JO - Nature Energy

JF - Nature Energy

IS - 10

ER -

Benchmarking the reproducibility of all-solid-state battery cell performance

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