An efficient synthesis of versatile terpyridine analogues for cyclometallated luminescent cyclodextrins

Murielle Chavarot; Zoe Pikramenou

doi:10.1016/S0040-4039(99)01386-6

An efficient synthesis of versatile terpyridine analogues for cyclometallated luminescent cyclodextrins

Murielle Chavarot, Zoe Pikramenou

Research output: Contribution to journal › Article › peer-review

21 Citations (Scopus)

Abstract

An efficient synthetic method for preparing functionalised terpyridyl analogues based on Negishi's zinc coupling is developed. These ligands form cyclometallated complexes; attaching them to cyclodextrins allows preparation of luminescent cyclometallated ruthenium cyclodextrins for the assembly of photoactive units via non-covalent interactions.

A one-pot synthesis of terpyridine analogues is used to form new cyclometallated ruthenium cyclodextrins.

Original language	English
Pages (from-to)	6865-6868
Number of pages	4
Journal	Tetrahedron Letters
Volume	40
Issue number	37
DOIs	https://doi.org/10.1016/S0040-4039(99)01386-6
Publication status	Published - 10 Sept 1999

Keywords

Negishi's cross-coupling
luminescent cyclodextrins
ruthenium complexes

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abstract = "An efficient synthetic method for preparing functionalised terpyridyl analogues based on Negishi's zinc coupling is developed. These ligands form cyclometallated complexes; attaching them to cyclodextrins allows preparation of luminescent cyclometallated ruthenium cyclodextrins for the assembly of photoactive units via non-covalent interactions.A one-pot synthesis of terpyridine analogues is used to form new cyclometallated ruthenium cyclodextrins.",

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AU - Chavarot, Murielle

AU - Pikramenou, Zoe

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N2 - An efficient synthetic method for preparing functionalised terpyridyl analogues based on Negishi's zinc coupling is developed. These ligands form cyclometallated complexes; attaching them to cyclodextrins allows preparation of luminescent cyclometallated ruthenium cyclodextrins for the assembly of photoactive units via non-covalent interactions.A one-pot synthesis of terpyridine analogues is used to form new cyclometallated ruthenium cyclodextrins.

AB - An efficient synthetic method for preparing functionalised terpyridyl analogues based on Negishi's zinc coupling is developed. These ligands form cyclometallated complexes; attaching them to cyclodextrins allows preparation of luminescent cyclometallated ruthenium cyclodextrins for the assembly of photoactive units via non-covalent interactions.A one-pot synthesis of terpyridine analogues is used to form new cyclometallated ruthenium cyclodextrins.

KW - Negishi's cross-coupling

KW - luminescent cyclodextrins

KW - ruthenium complexes

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U2 - 10.1016/S0040-4039(99)01386-6

DO - 10.1016/S0040-4039(99)01386-6

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EP - 6868

JO - Tetrahedron Letters

JF - Tetrahedron Letters

IS - 37

ER -

An efficient synthesis of versatile terpyridine analogues for cyclometallated luminescent cyclodextrins

Abstract

Keywords

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