Additive-Free Clicking for Polymer Functionalization and Coupling by Tetrazine-Norbornene Chemistry

Claire F. Hansell; Pieter Espeel; Milan M. Stamenovic; Ian A. Barker; Andrew P. Dove; Filip E. Du Prez; Rachel K. O'Reilly

doi:10.1021/ja203957h

Additive-Free Clicking for Polymer Functionalization and Coupling by Tetrazine-Norbornene Chemistry

Claire F. Hansell, Pieter Espeel, Milan M. Stamenovic, Ian A. Barker, Andrew P. Dove, Filip E. Du Prez, Rachel K. O'Reilly

Chemistry

Research output: Contribution to journal › Article › peer-review

134 Citations (Scopus)

Abstract

Herein we report the use of a tetrazine-norbornene inverse electron demand Diels–Alder conjugation applied to polymer end-functionalization and polymer–polymer coupling. The reaction was found to be applicable to polymer–polymer coupling, as judged by SEC, DOSY NMR, and LCxSEC analyses, giving diblock copolymers by merely mixing the constituent homopolymers together under ambient conditions, using no catalyst, additive, or external stimulus.

Original language	English
Pages (from-to)	13828-13831
Journal	Journal of the American Chemical Society
Volume	133
Issue number	35
DOIs	https://doi.org/10.1021/ja203957h
Publication status	Published - 5 Aug 2011

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10.1021/ja203957h

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abstract = "Herein we report the use of a tetrazine-norbornene inverse electron demand Diels–Alder conjugation applied to polymer end-functionalization and polymer–polymer coupling. The reaction was found to be applicable to polymer–polymer coupling, as judged by SEC, DOSY NMR, and LCxSEC analyses, giving diblock copolymers by merely mixing the constituent homopolymers together under ambient conditions, using no catalyst, additive, or external stimulus.",

author = "Hansell, {Claire F.} and Pieter Espeel and Stamenovic, {Milan M.} and Barker, {Ian A.} and Dove, {Andrew P.} and {Du Prez}, {Filip E.} and O'Reilly, {Rachel K.}",

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T1 - Additive-Free Clicking for Polymer Functionalization and Coupling by Tetrazine-Norbornene Chemistry

AU - Hansell, Claire F.

AU - Espeel, Pieter

AU - Stamenovic, Milan M.

AU - Barker, Ian A.

AU - Dove, Andrew P.

AU - Du Prez, Filip E.

AU - O'Reilly, Rachel K.

PY - 2011/8/5

Y1 - 2011/8/5

N2 - Herein we report the use of a tetrazine-norbornene inverse electron demand Diels–Alder conjugation applied to polymer end-functionalization and polymer–polymer coupling. The reaction was found to be applicable to polymer–polymer coupling, as judged by SEC, DOSY NMR, and LCxSEC analyses, giving diblock copolymers by merely mixing the constituent homopolymers together under ambient conditions, using no catalyst, additive, or external stimulus.

AB - Herein we report the use of a tetrazine-norbornene inverse electron demand Diels–Alder conjugation applied to polymer end-functionalization and polymer–polymer coupling. The reaction was found to be applicable to polymer–polymer coupling, as judged by SEC, DOSY NMR, and LCxSEC analyses, giving diblock copolymers by merely mixing the constituent homopolymers together under ambient conditions, using no catalyst, additive, or external stimulus.

UR - http://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=ORCID&SrcApp=OrcidOrg&DestLinkType=FullRecord&DestApp=WOS_CPL&KeyUT=WOS:000295241400017&KeyUID=WOS:000295241400017

U2 - 10.1021/ja203957h

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EP - 13831

JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

IS - 35

ER -

Additive-Free Clicking for Polymer Functionalization and Coupling by Tetrazine-Norbornene Chemistry

Abstract

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