Active template synthesis of rotaxanes and molecular shuttles with switchable dynamics by four-component PdII-promoted Michael additions

Stephen M. Goldup; David A. Leigh; Paul J. Lusby; Roy T. McBurney; Alexandra M.Z. Slawin

doi:10.1002/anie.200705859

Active template synthesis of rotaxanes and molecular shuttles with switchable dynamics by four-component Pd^II-promoted Michael additions

Stephen M. Goldup
, David A. Leigh
, Paul J. Lusby
, Roy T. McBurney
, Alexandra M.Z. Slawin

Chemistry

Research output: Contribution to journal › Article › peer-review

53 Citations (Scopus)

Abstract

(Chemical Equation). Taking the Michael: Rotaxanes (see structure) and molecular shuttles are prepared in up to 99% yield by successive Pd ^II-promoted 1,4-conjugate additions in a one-pot four-component assembly process. This process represents the first active template reaction in which the template motif is retained in the interlocked product.

Original language	English
Pages (from-to)	3381-3384
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	47
Issue number	18
DOIs	https://doi.org/10.1002/anie.200705859
Publication status	Published - 21 Apr 2008

Keywords

Lewis acid catalysts
Molecular shuttles
Palladium
Rotaxanes
Template synthesis

ASJC Scopus subject areas

Catalysis
General Chemistry

Access to Document

10.1002/anie.200705859

Cite this

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title = "Active template synthesis of rotaxanes and molecular shuttles with switchable dynamics by four-component PdII-promoted Michael additions",

abstract = "(Chemical Equation). Taking the Michael: Rotaxanes (see structure) and molecular shuttles are prepared in up to 99\% yield by successive Pd II-promoted 1,4-conjugate additions in a one-pot four-component assembly process. This process represents the first active template reaction in which the template motif is retained in the interlocked product.",

keywords = "Lewis acid catalysts, Molecular shuttles, Palladium, Rotaxanes, Template synthesis",

author = "Goldup, \{Stephen M.\} and Leigh, \{David A.\} and Lusby, \{Paul J.\} and McBurney, \{Roy T.\} and Slawin, \{Alexandra M.Z.\}",

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AU - Goldup, Stephen M.

AU - Leigh, David A.

AU - Lusby, Paul J.

AU - McBurney, Roy T.

AU - Slawin, Alexandra M.Z.

PY - 2008/4/21

Y1 - 2008/4/21

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AB - (Chemical Equation). Taking the Michael: Rotaxanes (see structure) and molecular shuttles are prepared in up to 99% yield by successive Pd II-promoted 1,4-conjugate additions in a one-pot four-component assembly process. This process represents the first active template reaction in which the template motif is retained in the interlocked product.

KW - Lewis acid catalysts

KW - Molecular shuttles

KW - Palladium

KW - Rotaxanes

KW - Template synthesis

UR - https://www.scopus.com/pages/publications/47949092622

U2 - 10.1002/anie.200705859

DO - 10.1002/anie.200705859

M3 - Article

AN - SCOPUS:47949092622

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