A novel polyoxometalate chain formed from heteropolyanion building blocks and rare earth metal ion linkers: [La(H2O)(7)Al(OH)(6)Mo6O18](n)center dot 4nH(2)O

V Shivaiah; PVN Reddy; Leroy Cronin; SK Das

doi:10.1039/b207149e

A novel polyoxometalate chain formed from heteropolyanion building blocks and rare earth metal ion linkers: [La(H2O)(7)Al(OH)(6)Mo6O18](n)center dot 4nH(2)O

V Shivaiah, PVN Reddy, Leroy Cronin, SK Das

Chemistry

Research output: Contribution to journal › Article

86 Citations (Scopus)

Abstract

The structure of the complex [La(H2O)(7)Al(OH)(6)Mo6O18](n). 4nH(2)O is the first example of a 1D extended chain in which an Anderson type heteropolyanion is linked by rare earth metal ions in zig-zag chains that arrange "head to tail" in the structure; furthermore the chains are themselves linked into an extensive three-dimensional hydrogen bonded network.

Original language	English
Pages (from-to)	3781-3782
Number of pages	2
Journal	Journal of the Chemical Society. Dalton Transactions
Issue number	20
DOIs	https://doi.org/10.1039/b207149e
Publication status	Published - 1 Jan 2002

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10.1039/b207149e

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abstract = "The structure of the complex [La(H2O)(7)Al(OH)(6)Mo6O18](n). 4nH(2)O is the first example of a 1D extended chain in which an Anderson type heteropolyanion is linked by rare earth metal ions in zig-zag chains that arrange {"}head to tail{"} in the structure; furthermore the chains are themselves linked into an extensive three-dimensional hydrogen bonded network.",

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AU - Reddy, PVN

AU - Cronin, Leroy

AU - Das, SK

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N2 - The structure of the complex [La(H2O)(7)Al(OH)(6)Mo6O18](n). 4nH(2)O is the first example of a 1D extended chain in which an Anderson type heteropolyanion is linked by rare earth metal ions in zig-zag chains that arrange "head to tail" in the structure; furthermore the chains are themselves linked into an extensive three-dimensional hydrogen bonded network.

AB - The structure of the complex [La(H2O)(7)Al(OH)(6)Mo6O18](n). 4nH(2)O is the first example of a 1D extended chain in which an Anderson type heteropolyanion is linked by rare earth metal ions in zig-zag chains that arrange "head to tail" in the structure; furthermore the chains are themselves linked into an extensive three-dimensional hydrogen bonded network.

U2 - 10.1039/b207149e

DO - 10.1039/b207149e

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JO - Journal of the Chemical Society. Dalton Transactions

JF - Journal of the Chemical Society. Dalton Transactions

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A novel polyoxometalate chain formed from heteropolyanion building blocks and rare earth metal ion linkers: [La(H2O)(7)Al(OH)(6)Mo6O18](n)center dot 4nH(2)O

Abstract

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