A mechanochemical strategy for oxidative addition: Remarkable yields and stereoselectivity in the halogenation of organometallic Re(I) complexes

José G. Hernández; Neil A.J. Macdonald; Cristina Mottillo; Ian S. Butler; Tomislav Friščić

doi:10.1039/c3gc42104j

A mechanochemical strategy for oxidative addition: Remarkable yields and stereoselectivity in the halogenation of organometallic Re(I) complexes

José G. Hernández, Neil A.J. Macdonald, Cristina Mottillo, Ian S. Butler^*, Tomislav Friščić

^*Corresponding author for this work

Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

A simple solvent-free mechanochemical procedure enables rapid and high-yielding oxidative halogenation of model organometallic Re(I) compounds with excellent and tunable stereoselectivity, demonstrating how mechanochemistry can advance and simplify fundamental organometallic transformations.

Original language	English
Pages (from-to)	1087-1092
Number of pages	6
Journal	Green Chemistry
Volume	16
Issue number	3
DOIs	https://doi.org/10.1039/c3gc42104j
Publication status	Published - Mar 2014

ASJC Scopus subject areas

Environmental Chemistry
Pollution

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title = "A mechanochemical strategy for oxidative addition: Remarkable yields and stereoselectivity in the halogenation of organometallic Re(I) complexes",

abstract = "A simple solvent-free mechanochemical procedure enables rapid and high-yielding oxidative halogenation of model organometallic Re(I) compounds with excellent and tunable stereoselectivity, demonstrating how mechanochemistry can advance and simplify fundamental organometallic transformations.",

author = "Hern{\'a}ndez, \{Jos{\'e} G.\} and Macdonald, \{Neil A.J.\} and Cristina Mottillo and Butler, \{Ian S.\} and Tomislav Fri{\v s}{\v c}i{\'c}",

year = "2014",

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AU - Mottillo, Cristina

AU - Butler, Ian S.

AU - Friščić, Tomislav

PY - 2014/3

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U2 - 10.1039/c3gc42104j

DO - 10.1039/c3gc42104j

M3 - Article

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JO - Green Chemistry

JF - Green Chemistry

IS - 3

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A mechanochemical strategy for oxidative addition: Remarkable yields and stereoselectivity in the halogenation of organometallic Re(I) complexes

Abstract

ASJC Scopus subject areas

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