A luminescent one-dimensional copper(I) polymer

Z. Pikramenou; G.A. Solan; R.E.P. Winpenny

doi:10.1023/a:1009077118047

A luminescent one-dimensional copper(I) polymer

Z. Pikramenou, G.A. Solan, R.E.P. Winpenny

Research output: Contribution to journal › Article › peer-review

8 Citations (Scopus)

Abstract

The synthesis and structure of a one-dimensional polymer of formula [Cu₃(dpphp)₂(MeCN)_1.7(CH₂Cl₂)_0.3](ClO₄) _n is reported (where dpphp=6-diphenylphosphino-2-pyridonate). There are three distinct copper(I) sites within the polymer. Two of these sites are four-coordinate, bound to one P- and two O-atoms and a solvate molecule; the third site is bound only to two N-atoms. The Cu*Cu distances within the polymer are around 2.8 Å. The compound is luminescent in the solid-state.

Original language	English
Pages (from-to)	227–232
Number of pages	6
Journal	Journal of Cluster Science
Volume	11
Issue number	1
DOIs	https://doi.org/10.1023/a:1009077118047
Publication status	Published - Mar 2000

Keywords

luminescent copper complex
one-dimensional polymer

Access to Document

10.1023/a:1009077118047Licence: None: All rights reserved

Cite this

@article{a53a3203122641eb9b7c45976b3455aa,

title = "A luminescent one-dimensional copper(I) polymer",

abstract = "The synthesis and structure of a one-dimensional polymer of formula [Cu3(dpphp)2(MeCN)1.7(CH2Cl2)0.3](ClO4) n is reported (where dpphp=6-diphenylphosphino-2-pyridonate). There are three distinct copper(I) sites within the polymer. Two of these sites are four-coordinate, bound to one P- and two O-atoms and a solvate molecule; the third site is bound only to two N-atoms. The Cu*Cu distances within the polymer are around 2.8 {\AA}. The compound is luminescent in the solid-state.",

keywords = "luminescent copper complex, one-dimensional polymer",

author = "Z. Pikramenou and G.A. Solan and R.E.P. Winpenny",

year = "2000",

month = mar,

doi = "10.1023/a:1009077118047",

language = "English",

volume = "11",

pages = "227–232",

journal = "Journal of Cluster Science",

issn = "1040-7278",

publisher = "Springer",

number = "1",

}

TY - JOUR

T1 - A luminescent one-dimensional copper(I) polymer

AU - Pikramenou, Z.

AU - Solan, G.A.

AU - Winpenny, R.E.P.

PY - 2000/3

Y1 - 2000/3

N2 - The synthesis and structure of a one-dimensional polymer of formula [Cu3(dpphp)2(MeCN)1.7(CH2Cl2)0.3](ClO4) n is reported (where dpphp=6-diphenylphosphino-2-pyridonate). There are three distinct copper(I) sites within the polymer. Two of these sites are four-coordinate, bound to one P- and two O-atoms and a solvate molecule; the third site is bound only to two N-atoms. The Cu*Cu distances within the polymer are around 2.8 Å. The compound is luminescent in the solid-state.

AB - The synthesis and structure of a one-dimensional polymer of formula [Cu3(dpphp)2(MeCN)1.7(CH2Cl2)0.3](ClO4) n is reported (where dpphp=6-diphenylphosphino-2-pyridonate). There are three distinct copper(I) sites within the polymer. Two of these sites are four-coordinate, bound to one P- and two O-atoms and a solvate molecule; the third site is bound only to two N-atoms. The Cu*Cu distances within the polymer are around 2.8 Å. The compound is luminescent in the solid-state.

KW - luminescent copper complex

KW - one-dimensional polymer

UR - http://www.scopus.com/inward/record.url?eid=2-s2.0-0034408525&partnerID=MN8TOARS

U2 - 10.1023/a:1009077118047

DO - 10.1023/a:1009077118047

M3 - Article

SN - 1040-7278

VL - 11

SP - 227

EP - 232

JO - Journal of Cluster Science

JF - Journal of Cluster Science

IS - 1

ER -

A luminescent one-dimensional copper(I) polymer

Abstract

Keywords

Access to Document

Fingerprint

Cite this