Abstract
The synthesis and structure of a one-dimensional polymer of formula [Cu3(dpphp)2(MeCN)1.7(CH2Cl2)0.3](ClO4) n is reported (where dpphp=6-diphenylphosphino-2-pyridonate). There are three distinct copper(I) sites within the polymer. Two of these sites are four-coordinate, bound to one P- and two O-atoms and a solvate molecule; the third site is bound only to two N-atoms. The Cu*Cu distances within the polymer are around 2.8 Å. The compound is luminescent in the solid-state.
Original language | English |
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Pages (from-to) | 227–232 |
Number of pages | 6 |
Journal | Journal of Cluster Science |
Volume | 11 |
Issue number | 1 |
DOIs | |
Publication status | Published - Mar 2000 |
Keywords
- luminescent copper complex
- one-dimensional polymer