A luminescent one-dimensional copper(I) polymer

Z. Pikramenou, G.A. Solan, R.E.P. Winpenny

Research output: Contribution to journalArticlepeer-review

8 Citations (Scopus)

Abstract

The synthesis and structure of a one-dimensional polymer of formula [Cu3(dpphp)2(MeCN)1.7(CH2Cl2)0.3](ClO4) n is reported (where dpphp=6-diphenylphosphino-2-pyridonate). There are three distinct copper(I) sites within the polymer. Two of these sites are four-coordinate, bound to one P- and two O-atoms and a solvate molecule; the third site is bound only to two N-atoms. The Cu*Cu distances within the polymer are around 2.8 Å. The compound is luminescent in the solid-state.
Original languageEnglish
Pages (from-to)227–232
Number of pages6
JournalJournal of Cluster Science
Volume11
Issue number1
DOIs
Publication statusPublished - Mar 2000

Keywords

  • luminescent copper complex
  • one-dimensional polymer

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