A high-resolution synchrotron X-ray powder diffraction study of trans-stilbene in zeolite ZSM-5

J. B. Parise; J. A. Hriljac; D. E. Cox; D. R. Corbin; V. Ramamurthy

doi:10.1039/C39930000226

A high-resolution synchrotron X-ray powder diffraction study of trans-stilbene in zeolite ZSM-5

J. B. Parise^*, J. A. Hriljac, D. E. Cox, D. R. Corbin, V. Ramamurthy

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

25 Citations (Scopus)

Abstract

Upon adsorption of two molecules of stilbene per unit cell, the apparent symmetry of ZSM-5 changes to tetragonal, but the true symmetry is orthorhombic with a very small difference between aand b, which becomes progressively more pronounced with b > aas the sample is cooled to 25 K; the stilbene molecule is located in the straight channels, with one phenyl ring on the mirror plane, at the intersection of the straight and sinusoidal channels.

Original language	English
Pages (from-to)	226-228
Number of pages	3
Journal	Journal of the Chemical Society Chemical Communications
Issue number	3
DOIs	https://doi.org/10.1039/C39930000226
Publication status	Published - 1993
Externally published	Yes

ASJC Scopus subject areas

Molecular Medicine

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10.1039/C39930000226

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title = "A high-resolution synchrotron X-ray powder diffraction study of trans-stilbene in zeolite ZSM-5",

abstract = "Upon adsorption of two molecules of stilbene per unit cell, the apparent symmetry of ZSM-5 changes to tetragonal, but the true symmetry is orthorhombic with a very small difference between aand b, which becomes progressively more pronounced with b > aas the sample is cooled to 25 K; the stilbene molecule is located in the straight channels, with one phenyl ring on the mirror plane, at the intersection of the straight and sinusoidal channels.",

author = "Parise, {J. B.} and Hriljac, {J. A.} and Cox, {D. E.} and Corbin, {D. R.} and V. Ramamurthy",

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journal = "Journal of the Chemical Society Chemical Communications",

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AU - Parise, J. B.

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AU - Cox, D. E.

AU - Corbin, D. R.

AU - Ramamurthy, V.

PY - 1993

Y1 - 1993

N2 - Upon adsorption of two molecules of stilbene per unit cell, the apparent symmetry of ZSM-5 changes to tetragonal, but the true symmetry is orthorhombic with a very small difference between aand b, which becomes progressively more pronounced with b > aas the sample is cooled to 25 K; the stilbene molecule is located in the straight channels, with one phenyl ring on the mirror plane, at the intersection of the straight and sinusoidal channels.

AB - Upon adsorption of two molecules of stilbene per unit cell, the apparent symmetry of ZSM-5 changes to tetragonal, but the true symmetry is orthorhombic with a very small difference between aand b, which becomes progressively more pronounced with b > aas the sample is cooled to 25 K; the stilbene molecule is located in the straight channels, with one phenyl ring on the mirror plane, at the intersection of the straight and sinusoidal channels.

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DO - 10.1039/C39930000226

M3 - Article

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A high-resolution synchrotron X-ray powder diffraction study of trans-stilbene in zeolite ZSM-5

Abstract

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