Abstract
An efficient C-O, C-S and C-C bond-forming sequence leads to functionalised compounds bearing sulfur-substituted quaternary carbons. Ynamides are employed as diazo-equivalents to access the [2,3]-sigmatropic rearrangements of allyl sulfonium ylides by a three-component chemoselective oxidation and intermolecular ylide formation.
| Original language | English |
|---|---|
| Pages (from-to) | 6001-6004 |
| Number of pages | 4 |
| Journal | Chemical Communications |
| Volume | 50 |
| Issue number | 45 |
| Early online date | 16 Apr 2014 |
| DOIs | |
| Publication status | Published - 7 Jun 2014 |
ASJC Scopus subject areas
- General Chemistry
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Dive into the research topics of 'A gold-catalysed fully intermolecular oxidation and sulfur-ylide formation sequence on ynamides'. Together they form a unique fingerprint.Research output
- 66 Citations
- 3 Article
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A gold carbene manifold to prepare fused γ-lactams by oxidative cyclisation of ynamides
Davies, P., Priest, J. & Sanchez-Cantalejo, F., 22 Nov 2018, In: Chemistry: A European Journal. 24, 65, p. 17215-17219Research output: Contribution to journal › Article › peer-review
Open AccessFile20 Citations (Scopus)212 Downloads (Pure) -
Synthesis of N-Acyl pyridinium-N-aminides and their conversion to 4-aminooxazoles via a gold-catalyzed formal (3+2)-dipolar cycloaddition
Davies, P., Jannapureddy, R. & Ball, M., 2018, In: Organic Syntheses. 95, p. 112-126 15 p.Research output: Contribution to journal › Article › peer-review
1 Citation (Scopus) -
Alkynyl sulfoxides as α-sulfinyl carbene equivalents: Gold-catalysed oxidative cyclopropanation
Barrett, M., Khan, G., Davies, P. & Grainger, R., 25 May 2017, In: Chemical Communications . 53, 42, p. 5733-5736 4 p.Research output: Contribution to journal › Article › peer-review
Open AccessFile20 Citations (Scopus)259 Downloads (Pure)
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