A gold-catalysed fully intermolecular oxidation and sulfur-ylide formation sequence on ynamides

Mickaël Dos Santos, Paul W. Davies

Research output: Contribution to journalArticlepeer-review

66 Citations (Scopus)
238 Downloads (Pure)

Abstract

An efficient C-O, C-S and C-C bond-forming sequence leads to functionalised compounds bearing sulfur-substituted quaternary carbons. Ynamides are employed as diazo-equivalents to access the [2,3]-sigmatropic rearrangements of allyl sulfonium ylides by a three-component chemoselective oxidation and intermolecular ylide formation.

Original languageEnglish
Pages (from-to)6001-6004
Number of pages4
JournalChemical Communications
Volume50
Issue number45
Early online date16 Apr 2014
DOIs
Publication statusPublished - 7 Jun 2014

ASJC Scopus subject areas

  • Chemistry(all)

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