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Four organometallic nucleobases have been prepared and characterized, each consisting of a disubstituted ferrocene unit connected through either a conjugated or saturated linker group to adenine or thymine nucleobases. Their assembly behavior has been studied in the solid state via X-ray crystallography, revealing intermolecular H-bonded arrays. The electrode potentials in DCM are strongly dependent upon the nature of the linker group between the ferrocene unit and the nucleobase.
|Number of pages||7|
|Publication status||Published - 1 Oct 2011|
FingerprintDive into the research topics of '1,1 '-Homodisubstituted Ferrocenes Containing Adenine and Thymine Nucleobases: Synthesis, Electrochemistry, and Formation of H-Bonded Arrays'. Together they form a unique fingerprint.
- 1 Finished
Functional DNA-based assemblies
Engineering & Physical Science Research Council
16/03/09 → 31/03/14
Project: Research Councils