Stephen Goldup

2024

A Platform Approach to Cleavable Macrocycles for the Controlled Disassembly of Mechanically Caged Molecules

Saady, A., Malcolm, G., Fitzpatrick, M., Pairault, N., Tizzard, G., Mohammed, S., Tavassoli, A. & Goldup, S., 6 Mar 2024, In: Angewandte Chemie (International Edition) . 2024, 7 p., e202400344.

Research output: Contribution to journal › Article › peer-review

Open Access

File

80 Downloads (Pure)

Facial Selectivity in Mechanical Bond Formation: Axially Chiral Enantiomers and Geometric Isomers from a Simple Prochiral Macrocycle

Gallagher, P., Savoini, A., Saady, A., Maynard, J. R. J., Butler, P., Tizzard, G. J. & Goldup, S., 20 Mar 2024, (E-pub ahead of print) In: Journal of the American Chemical Society.

Research output: Contribution to journal › Article › peer-review

Open Access

File

108 Downloads (Pure)

Steric Engineering of Rotaxane Catalysts: Benefits and Limits of Using the Mechanical Bond in Catalyst Design

Struth, F. R., Jansen, D., Pairault, N., Schumacher, M., Uteschil, F., Linders, J., Mayer, C., Gröschel, A. H., Goldup, S. M. & Niemeyer, J., 14 Aug 2024, (E-pub ahead of print) In: Chemistry: A European Journal. e202402717.

Research output: Contribution to journal › Article › peer-review

Open Access

File

35 Downloads (Pure)

The End of the Beginning of Mechanical Stereochemistry

Goldup, S. M., 18 Jun 2024, In: Accounts of Chemical Research. 57, 12, p. 1696-1708 13 p.

Research output: Contribution to journal › Article › peer-review

Open Access

File

79 Downloads (Pure)

The Final Stereogenic Unit of [2]Rotaxanes: Type 2 Geometric Isomers

Savoini, A., Gallagher, P., Saady, A. & Goldup, S., 18 Mar 2024, (E-pub ahead of print) In: Journal of the American Chemical Society. 8 p.

Research output: Contribution to journal › Article › peer-review

Open Access

File

52 Downloads (Pure)

2023

A catenane that is topologically achiral despite being composed of oriented rings

Pairault, N., Rizzi, F., Lozano, D., Jamieson, E. M. G., Tizzard, G. J. & Goldup, S. M., Jun 2023, In: Nature Chemistry. 15, 6, p. 781–786 6 p.

Research output: Contribution to journal › Article › peer-review

Open Access

File

66 Downloads (Pure)

A chiral macrocycle for the stereoselective synthesis of mechanically planar chiral rotaxanes and catenanes

Zhang, S., Rodríguez-Rubio, A., Saady, A., Tizzard, G. J. & Goldup, S. M., 11 May 2023, In: Chem. 9, 5, p. 1195-1207 14 p.

Research output: Contribution to journal › Article › peer-review

Open Access

File

85 Downloads (Pure)

Non-equilibrium Steady States in Catalysis, Molecular Motors, and Supramolecular Materials: Why Networks and Language Matter

Aprahamian, I. & Goldup, S. M., 5 Jul 2023, In: Journal of the American Chemical Society. 145, 26, p. 14169-14183 15 p.

Research output: Contribution to journal › Article › peer-review

Open Access

File

134 Downloads (Pure)

Triazole formation and the click concept in the synthesis of interlocked molecules

Saady, A. & Goldup, S. M., 10 Aug 2023, In: Chem. 9, 8, p. 2110-2127

Research output: Contribution to journal › Article › peer-review

Open Access

File

75 Downloads (Pure)

2022

A chiral interlocking auxiliary strategy for the synthesis of mechanically planar chiral rotaxanes

de Juan, A., Lozano, D., Heard, A. W., Jinks, M. A., Suarez, J. M., Tizzard, G. J. & Goldup, S. M., Feb 2022, In: Nature Chemistry. 14, 2, p. 179-187 9 p.

Research output: Contribution to journal › Article › peer-review

13 Citations (Scopus)

A co-conformationally "topologically" chiral catenane

Rodríguez-Rubio, A., Savoini, A., Modicom, F., Butler, P. & Goldup, S. M., 13 Jul 2022, In: Journal of the American Chemical Society. 144, 27, p. 11927-11932 6 p.

Research output: Contribution to journal › Article › peer-review

Open Access

File

2 Citations (Scopus)

75 Downloads (Pure)

Anion–π catalysis enabled by the mechanical bond**

Maynard, J. R. J., Galmés, B., Stergiou, A. D., Symes, M. D., Frontera, A. & Goldup, S. M., 14 Mar 2022, In: Angewandte Chemie - International Edition. 61, 12, 8 p., e202115961.

Research output: Contribution to journal › Article › peer-review

Open Access

File

4 Citations (Scopus)

55 Downloads (Pure)

Author correction: A chiral interlocking auxiliary strategy for the synthesis of mechanically planar chiral rotaxanes

de Juan, A., Lozano, D., Heard, A. W., Jinks, M. A., Suarez, J. M., Tizzard, G. J. & Goldup, S. M., Feb 2022, In: Nature Chemistry. 14, 2, p. 239-239 1 p.

Research output: Contribution to journal › Comment/debate › peer-review

Controlling catalyst activity, chemoselectivity and stereoselectivity with the mechanical bond

Heard, A. W., Suárez, J. M. & Goldup, S. M., Mar 2022, In: Nature Reviews Chemistry. 6, 3, p. 182-196 15 p.

Research output: Contribution to journal › Review article › peer-review

11 Citations (Scopus)

Direct detection of hydrogen bonds in supramolecular systems using ¹H-¹⁵N Heteronuclear multiple quantum coherence spectroscopy

Jinks, M. A., Howard, M., Rizzi, F., Goldup, S. M., Burnett, A. D. & Wilson, A. J., 21 Dec 2022, In: Journal of the American Chemical Society. 144, 50, p. 23127-23133 7 p.

Research output: Contribution to journal › Article › peer-review

Open Access

File

80 Downloads (Pure)

Mechanically axially chiral catenanes and noncanonical mechanically axially chiral rotaxanes

Maynard, J. R. J., Gallagher, P., Lozano, D., Butler, P. & Goldup, S. M., Sept 2022, In: Nature Chemistry. 14, 9, p. 1038-1044 7 p.

Research output: Contribution to journal › Article › peer-review

4 Citations (Scopus)

2021

Damming an electronic energy reservoir: ion-regulated electronic energy shuttling in a [2]rotaxane

Yu, S., Kupryakov, A., Lewis, J. E. M., Martí-Centelles, V., Goldup, S. M., Pozzo, J. L., Jonusauskas, G. & McClenaghan, N. D., 14 Jul 2021, In: Chemical Science. 12, 26, p. 9196-9200 5 p.

Research output: Contribution to journal › Article › peer-review

Open Access

File

2 Citations (Scopus)

70 Downloads (Pure)

Rotaxane Co^II complexes as field-induced single-ion magnets

Cirulli, M., Salvadori, E., Zhang, Z., Dommett, M., Tuna, F., Bamberger, H., Lewis, J. E. M., Kaur, A., Tizzard, G. J., Slageren, J., Crespo‐otero, R., Goldup, S. M. & Roessler, M. M., 12 Jul 2021, In: Angewandte Chemie (International Edition) . 60, 29, p. 16051-16058 8 p.

Research output: Contribution to journal › Article › peer-review

Open Access

File

37 Downloads (Pure)

Spin-labelled mechanically interlocked molecules as models for the interpretation of biradical EPR spectra

Gualandi, L., Franchi, P., Mezzina, E., Goldup, S. M. & Lucarini, M., 28 Jun 2021, In: Chemical Science. 12, 24, p. 8385-8393 9 p.

Research output: Contribution to journal › Article › peer-review

Open Access

File

2 Citations (Scopus)

54 Downloads (Pure)

Synthesis, photophysical and assembly studies of novel luminescent lanthanide(III) complexes of 1,2,3-triazolyl-pyridine-2,6-dicarboxamide-based ligands

O’Neil, A. T., Zhang, N., Harrison, J. A., Goldup, S. M. & Kitchen, J. A., 18 Aug 2021, In: Supramolecular Chemistry. 33, 5, p. 160-173 14 p.

Research output: Contribution to journal › Article › peer-review

2 Citations (Scopus)

Using the mechanical bond to tune the performance of a thermally activated delayed fluorescence emitter**

Rajamalli, P., Rizzi, F., Li, W., Jinks, M. A., Gupta, A. K., Laidlaw, B. A., Samuel, I. D. W., Penfold, T. J., Goldup, S. M. & Zysman-Colman, E., 17 May 2021, In: Angewandte Chemie - International Edition. 60, 21, p. 12066-12073 8 p.

Research output: Contribution to journal › Article › peer-review

Open Access

File

17 Citations (Scopus)

81 Downloads (Pure)

2020

AT-CuAAC Synthesis of Mechanically Interlocked Oligonucleotides

Acevedo-Jake, A., Ball, A. T., Galli, M., Kukwikila, M., Denis, M., Singleton, D. G., Tavassoli, A. & Goldup, S. M., 1 Apr 2020, In: Journal of the American Chemical Society. 142, 13, p. 5985-5990 6 p.

Research output: Contribution to journal › Article › peer-review

Open Access

19 Citations (Scopus)

La SECO, témoignages de participants

Translated title of the contribution: Week of Study in Organic Chemistry (SECO), testimonials of participantsEchavarren, A., Frantz, M. C., Goldup, S., Lacour, J., Moreau, P. & Rademann, J., Aug 2020, In: Actualite Chimique. 453, p. 9-11 3 p.

Research output: Contribution to journal › Short survey › peer-review

Rotaxanation as a sequestering template to preclude incidental metal insertion in complex oligochromophores

Ngo, H. T., Lewis, J. E. M., Payne, D. T., D'Souza, F., Hill, J. P., Ariga, K., Yoshikawa, G. & Goldup, S. M., 11 Jul 2020, In: Chemical Communications. 56, 54, p. 7447-7450 4 p.

Research output: Contribution to journal › Article › peer-review

Rotaxane pt^II-complexes: Mechanical bonding for chemically robust luminophores and stimuli responsive behaviour

Zhang, Z., Tizzard, G. J., Williams, J. A. G. & Goldup, S. M., 21 Feb 2020, In: Chemical Science. 11, 7, p. 1839-1847 9 p.

Research output: Contribution to journal › Article › peer-review

Open Access

16 Citations (Scopus)

Simplicity in the Design, Operation, and Applications of Mechanically Interlocked Molecular Machines

Heard, A. W. & Goldup, S. M., 26 Feb 2020, In: ACS Central Science. 6, 2, p. 117-128 12 p.

Research output: Contribution to journal › Article › peer-review

Open Access

76 Citations (Scopus)

Strategies for the Synthesis of Enantiopure Mechanically Chiral Molecules

Maynard, J. R. J. & Goldup, S. M., 6 Aug 2020, In: Chem. 6, 8, p. 1914-1932 19 p.

Research output: Contribution to journal › Review article › peer-review

Open Access

35 Citations (Scopus)

Synthesis of a Mechanically Planar Chiral Rotaxane Ligand for Enantioselective Catalysis

Heard, A. W. & Goldup, S. M., 9 Apr 2020, In: Chem. 6, 4, p. 994-1006 13 p.

Research output: Contribution to journal › Article › peer-review

Open Access

69 Citations (Scopus)

Vibrational circular dichroism spectroscopy for probing the expression of chirality in mechanically planar chiral rotaxanes

Koenis, M. A. J., Chibueze, C. S., Jinks, M. A., Nicu, V. P., Visscher, L., Goldup, S. M. & Buma, W. J., 28 Aug 2020, In: Chemical Science. 11, 32, p. 8469-8475 7 p.

Research output: Contribution to journal › Article › peer-review

Open Access

11 Citations (Scopus)

2019

An Auxiliary Approach for the Stereoselective Synthesis of Topologically Chiral Catenanes

Denis, M., Lewis, J. E. M., Modicom, F. & Goldup, S. M., 13 Jun 2019, In: Chem. 5, 6, p. 1512-1520 9 p.

Research output: Contribution to journal › Article › peer-review

Open Access

39 Citations (Scopus)

Chemical Consequences of the Mechanical Bond: A Tandem Active Template-Rearrangement Reaction

Modicom, F., Jamieson, E. M. G., Rochette, E. & Goldup, S. M., 18 Mar 2019, In: Angewandte Chemie - International Edition. 58, 12, p. 3875-3879 5 p.

Research output: Contribution to journal › Article › peer-review

Open Access

19 Citations (Scopus)

Chirality makes a move

Jamieson, E. M. G. & Goldup, S. M., 1 Sept 2019, In: Nature Chemistry. 11, 9, p. 765-767 3 p.

Research output: Contribution to journal › Comment/debate › peer-review

6 Citations (Scopus)

Correction to: A simple, short, and flexible synthesis of viridiofungin derivatives (Journal of Organic Chemistry (2006) 71:16 (6185-6191) DOI: 10.1021/jo060931e)

Goldup, S. M., Pilkington, C. J., White, A. J. P., Burton, A. & Barrett, A. G. M., 17 May 2019, In: Journal of Organic Chemistry. 84, 10, p. 6546 1 p.

Research output: Contribution to journal › Comment/debate › peer-review

Open Access

Rotaxane-Based Transition Metal Complexes: Effect of the Mechanical Bond on Structure and Electronic Properties

Cirulli, M., Kaur, A., Lewis, J. E. M., Zhang, Z., Kitchen, J. A., Goldup, S. M. & Roessler, M. M., 16 Jan 2019, In: Journal of the American Chemical Society. 141, 2, p. 879-889 11 p.

Research output: Contribution to journal › Article › peer-review

35 Citations (Scopus)

2018

A [3]Rotaxane Host Selects Between Stereoisomers

Denis, M. & Goldup, S. M., 16 Apr 2018, In: Angewandte Chemie - International Edition. 57, 17, p. 4462-4464 3 p.

Research output: Contribution to journal › Comment/debate › peer-review

7 Citations (Scopus)

A Fluorescent Ditopic Rotaxane Ion-Pair Host

Denis, M., Qin, L., Turner, P., Jolliffe, K. A. & Goldup, S. M., 4 May 2018, In: Angewandte Chemie - International Edition. 57, 19, p. 5315-5319 5 p.

Research output: Contribution to journal › Article › peer-review

Open Access

38 Citations (Scopus)

Chelating Rotaxane Ligands as Fluorescent Sensors for Metal Ions

Denis, M., Pancholi, J., Jobe, K., Watkinson, M. & Goldup, S. M., 4 May 2018, In: Angewandte Chemie - International Edition. 57, 19, p. 5310-5314 5 p.

Research output: Contribution to journal › Article › peer-review

Open Access

54 Citations (Scopus)

Chirality in rotaxanes and catenanes

Jamieson, E. M. G., Modicom, F. & Goldup, S. M., 21 Jul 2018, In: Chemical Society Reviews. 47, 14, p. 5266-5311 46 p.

Research output: Contribution to journal › Article › peer-review

Open Access

148 Citations (Scopus)

Efficient Multicomponent Active Template Synthesis of Catenanes

Lewis, J. E. M., Modicom, F. & Goldup, S. M., 11 Apr 2018, In: Journal of the American Chemical Society. 140, 14, p. 4787-4791 5 p.

Research output: Contribution to journal › Article › peer-review

Open Access

28 Citations (Scopus)

Molecular machines swap rings news-and-views

Goldup, S., 3 May 2018, In: Nature. 557, 7703, p. 39-40 2 p.

Research output: Contribution to journal › Review article › peer-review

Open Access

5 Citations (Scopus)

Stereoselective Synthesis of Mechanically Planar Chiral Rotaxanes

Jinks, M. A., de Juan, A., Denis, M., Fletcher, C. J., Galli, M., Jamieson, E. M. G., Modicom, F., Zhang, Z. & Goldup, S. M., 5 Nov 2018, In: Angewandte Chemie - International Edition. 57, 45, p. 14806-14810 5 p.

Research output: Contribution to journal › Article › peer-review

Open Access

46 Citations (Scopus)

Synthesis and Characterisation of a Paramagnetic [2]Rotaxane Based on a Crown Ether-Like Wheel Incorporating a Nitroxide Motif

Bleve, V., Franchi, P., Konstanteli, E., Gualandi, L., Goldup, S. M., Mezzina, E. & Lucarini, M., 24 Jan 2018, In: Chemistry - A European Journal. 24, 5, p. 1198-1203 6 p.

Research output: Contribution to journal › Article › peer-review

8 Citations (Scopus)

2017

Metal ions in the synthesis of interlocked molecules and materials

Lewis, J. E. M., Beer, P. D., Loeb, S. J. & Goldup, S. M., 7 May 2017, In: Chemical Society Reviews. 46, 9, p. 2577-2591 15 p.

Research output: Contribution to journal › Review article › peer-review

135 Citations (Scopus)

Outstanding Reviewers for Chemical Society Reviews in 2016

Bisht, K., Goldup, S., Hutchings, G., Konig, B., Lovell, J., Manners, I., Qiao, S., Rivard, E., Ulijn, R. & Zhang, H., 21 May 2017, In: Chemical Society Reviews. 46, 10, p. 2659 1 p.

Research output: Contribution to journal › Editorial › peer-review

1 Citation (Scopus)

Porphyrinoid rotaxanes: Building a mechanical picket fence

Ngo, T. H., Labuta, J., Lim, G. N., Webre, W. A., D'Souza, F., Karr, P. A., Lewis, J. E. M., Hill, J. P., Ariga, K. & Goldup, S. M., 2017, In: Chemical Science. 8, 9, p. 6679-6685 7 p.

Research output: Contribution to journal › Article › peer-review

Open Access